General Chemistry 1: Exam 1

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Majority of the things are conceptual and not the actual math equations Also, for the SI conversions, I the exponents appear as subscripts for some reason, but they’re not. The numbers should be exponents.

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66 Terms

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tera (T)

1×1012

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giga (G)

1×109

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mega (M)

1×106

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kilo (k)

1×103

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hecto (h)

1×102

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deka (da)

1×101

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deci (d)

1×10-1

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centi [c]

1×10-2

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milli (m)

1×10-3

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micro (µ)

1×10-6

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nano (n)

1×10-9

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pico (p)

1×10-12

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femto (f)

1×10-15

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ºCelcius to Kelvin

K = ºC + 273.15

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Kelvin to ºCelcius

ºC = K - 273.15

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ºCelcius to ºFarenheit

ºF = (ºC × 9/5) + 32

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ºFarenheit to ºCelcius

ºC = (ºF - 32) × 5/9

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Atomic symbol, number, and mass

X = Atomic symbol of the element

A = mass number; A = Z + N

Z = atomic number (number of protons in nucleus)

N = number of neutrons in nucleus

<p>X = Atomic symbol of the element</p><p>A = mass number; A = Z + N</p><p>Z = atomic number (number of protons in nucleus)</p><p>N = number of neutrons in nucleus</p>
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Periodic Table Information

Rows = periods (electron shells)

Columns = Groups (valence electrons present)

Yellow = Akali Metals

Orange = Akali Earth Metals

Blue = Transition Metals

Navy = Post Transition Metals

Gray = Metalloids

Pink = Nonmetals

Light Blue = Halogens

Purple = Noble Gasses

<p>Rows = periods (electron shells)</p><p>Columns = Groups (valence electrons present)</p><p><span style="color: yellow">Yellow</span> = Akali Metals</p><p><span style="color: #ec9b12">Orange</span> = Akali Earth Metals </p><p><span style="color: #09517d">Blue</span> = Transition Metals</p><p><span style="color: #001329">Navy</span> = Post Transition Metals</p><p><span style="color: #838383">Gray</span> = Metalloids</p><p><span style="color: #af007d">Pink</span> = Nonmetals</p><p><span style="color: #00b2fb">Light Blue</span> = Halogens</p><p><span style="color: #5c2666">Purple</span> = Noble Gasses</p>
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Lewis Structure Example

Two dots = lone pair

One dot = covalent bonds possible

<p>Two dots = lone pair</p><p>One dot = covalent bonds possible</p>
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Periodic Table with Charges

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Polyatomic ion

A charged species consisting of two or more atoms covalently bonded together

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ammonium

NH4 +

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nitrite

NO2 -

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nitrate

NO3 -

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sulfite

SO32

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sulfate

SO42-

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hydrogen sulfate (aka: bisulfate)

HSO4-

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thiosulfate

S2O32-

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oxalate

C2O42-

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hydroxide

OH-

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peroxide

O22-

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cyanide

CN-

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phosphite

PO33-

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phosphate

PO43-

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hydrogen phosphate

HPO42-

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dihydrogen phosphate

H2PO4-

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perchlorate

ClO4-

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chlorate

ClO3-

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chlorite

ClO2-

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hypochlorite

ClO-

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bromate

BrO3-

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iodate

IO3-

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acetate

CH3COO-

and/or

C2H3O2-

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carbonate

CO32-

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hydrogen carbonate (aka: bicarbonate)

HCO3-

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chromate

CrO42-

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dichromate

Cr2O72-

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permanganate

MnO4-

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cyanate

OCN-

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thiocyanate

SCN-

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Naming binary compounds

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Prefixes and name endings for compounds

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Common names of compounds

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Avogadro’s number:

1 mol = 6.022×1023

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Calculating % composition

% of element = (mass of specific element/mass of whole compound) x100

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Calculating % yield

% yield = (actual yield/theoretical yield) x100

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significance of the photoelectric effect experiments on understanding of atomic structure (part 1)

- Electrons ejected when frequency over a threshold frequency

- Size of current is proportional to the intensity of incident light

<p>- Electrons ejected when frequency over a threshold frequency</p><p>- Size of current is proportional to the intensity of incident light</p>
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significance of the photoelectric effect experiments on understanding of atomic structure (part 2)

  • Electrons ejected when frequency over a threshold frequency

  • Size of current is proportional to the intensity of incident light

<ul><li><p><span>Electrons ejected when frequency over a threshold frequency</span></p></li><li><p><span>Size of current is proportional to the intensity of incident light</span></p></li></ul>
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Describe the electronic structure of the atom in terms of energy levels

Closer to nucleus = lower E

  • e- prefer to occupy lowest E state available

In the ground state of the atom

  • all e- are in lowest possible E level

<p>Closer to nucleus = lower E</p><ul><li><p>e<sup>- </sup> prefer to occupy lowest <em>E</em> state available</p></li></ul><p></p><p>In the ground state of the atom</p><ul><li><p>all e<sup>-</sup> are in lowest possible <em>E </em>level</p></li></ul><p></p>
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How do electrons move between energy levels within the atom

To move to a higher E level

  • the e must absorb a photon

  • that has the correct v and E

  • E must match ΔE between levels.

To drop back to a lower E level

  • the e must emit a photon

  • with the correct v and E.

<p><u>To move to a </u><span style="color: rgb(82, 246, 15)"><u>higher</u></span><u> E level</u></p><ul><li><p>the e must absorb a photon</p></li><li><p>that has the correct v and E</p></li><li><p>E must match ΔE between levels.</p></li></ul><p></p><p><u>To drop back to a </u><span style="color: red"><u>lower</u></span><u> E level</u></p><ul><li><p>the e must emit a photon</p></li><li><p>with the correct v and E.</p></li></ul><p></p>
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What is C?

  • speed of light

  • 2.998×108 m/s (constant)

  • c = ⋎*λ

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What is ⋎?

frequency

  • ⋎ = c/λ

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What is λ?

Wavelength

  • λ = c/⋎

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What is h?

6.626 × 10-34 J*s (constant)

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How do you find E?

E = (h x c)/(λ)

( 6.626 × 10-34J*s x 2.998 × 108m/s )/(λ)