Topic 7

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Dynamic equilibrium

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18 Terms

1

Dynamic equilibrium

A closed system with equal rate and concentration of forward and reverse reactions.

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2

Closed system

matter and energy can’t be lost or gained

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3

Open system

Matter and energy can escape

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4

Effect of pressure on equilibrium

increase = equilibrium shifts to side with less volume/number of molecules

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5

Effect of concentration on equilibrium

increase = forward reaction is favored

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6

Effects of temperature on equilibrium

increase = endothermic reaction is favored

only factor effecting Kc

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7

effect of Catalyst on equilibrium

Increase rate of both reactions

No effect on equilibrium

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8

Kc > 1

concentration of product is greater

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9

What factor effects Kc?

Temperature

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10

What happens to Kc if you reverse the equation?

It becomes the reciprocal

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11

What is Q?

Ratio of products and reactants for a reaction that hasn’t reached equilibrium

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12

What is the relationship between Q and Kc at equilibrium?

Q=Kc

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13

What happens if Q>Kc?

The reverse reaction is favored

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14

What happens if Q<Kc?

The forward reaction is favored

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15

Le Chatelier principle

If a change is made to a system at dynamic equilibrium, the position of the equilibrium moves to minimise this change

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16

What happens to Kc when reaction coefficients are doubled?

Kc is squared

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17

What happens to Kc when reaction coefficients are halved?

Kc is square rooted

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18

What happens to Kc if 2 reactions are added?

The Kc values are multiplied

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