Synthesis of acid chloride from cooh

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Last updated 5:26 AM on 8/10/26
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5 Terms

1
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addn/elim r-cooh to r-cocl

socl2 and heat to make acid chloride AND SO2 and HCl

KNOW MECHANISM

2
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what is special about the products of previous rxn

HCl is harsh cannot have ethers (cleaved) or alkenes (addn)

SO2 gas entropy helps

3
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addn/elim r-cooh to r-cocl

oxalyl chloride and na2co3 and benzene to acid chloride and CO2 and CO

KNOW MECHANISM

4
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what is special about the products of previous rxn

gentler conditions, no hcl side product

conditions tolerant to more functional groups


entropy and le chatelier’s helps drive reaction co2 and co bubble out


can be further reacted with r-oh to make ester (KNOW MECHANISM)


can be further reacted with r-nh2 to make amide (KNOW MECHANISM)

5
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alternate reagents r-cooh to r-cocl

r-cooh with PCl3 or PCl5 to r-cocl