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Kinetic Theory of Gases
Constant random high speed, directly proportional to temperature
Gas Pressure
Molecules colliding with each other and the wall
Basic Assumption 1
No energy is lost during molecular collision
Basic Assumption 2
Volume of the molecules themselves are negligible
Basic Assumption 3
no forces of mutual attraction exist between these molecules
Pressure
The force exerted per unit area
Volume
The space the gas occupies
Temperature
A measure of kinetic energy
Amount
The quantity of gas measured in moles
Critical Rule for temperature
All gas laws must be converted to Kelvin
ATM at sea level
1
Torr at sea level
760
mmHg at sea level
760
cmH2O at sea level
1034
PSI at sea level
14.7
cmHg at sea level
76
Gas conversion formula
(given pressure/ Given p. at sea level) X desired p. at sea level
Avogadro’s law
1 mole of any ideal gas occupies 22.4 liters at STP
STP
standard temp and pressure
1 mole
6.02 X 10²³
Avogadro’s law formula
Density= gram molecular weight (g/mol) / 22.4 (L/mol)
Density of air
1.25 g/L
Density of Helium
0.18 g/L
Boyle’s law
The volume of a gas is inversely proportional to its pressure
Boyle’s law formula
P1 V1= P2V2
Charles’s law
The volume of a gas is directly proportional to its absolute temperature
Charles’s law formula
V1/T1 = V2 / T2
Gay- Lussac’s law
The pressure of a gas is directly proportional to its absolute temperature.
Gay- Lussac’s law formula
P1/T1= P2/T2
The combined gas law
All 3 previous ones combined, pressure, volume and temperature
The combined gas law formula
(P1V1) / T1= (P2V2)/ T2
Dalton’s law of partial pressures
The total pressure of a gas mixture is equal to the sum of the partial pressures of each individual gas in the mixture
Dalton’s law of partial pressures formula
P total = P1 + P2 + P3 …
gas make up of oxygen
21%
gas make up for nitrogen
78%
Henry’s law
The higher the pressure if a gas above a liquid the more of it will dissolve into the liquid
critical temperature
the highest temperature at which a substance can exist as a liquid regardless of pressure
critical pressure
the pressure required to keep a substance in its liquid state at its critical temperature