Transition metal ligand names

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34 Terms

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aqua

H2O

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ammine

NH3

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carbonyl

CO

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methylamine

CH3NH2

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nitrosyl

NO

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pyridine

C5H5N

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ethylenediamine (en)

NH2CH2CH2NH2

polydentate, usually bi

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oxalato (ox)

C2O42-

bidentate

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ethylenediaminetetraacetic acid (EDTA)

C10H16N2O84-

hexadentate

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diethylenetriamine (dien)

(NH2CH2CH2)2NH

tridentate

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fluoro

F-

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chloro

Cl-

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bromo

Br-

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iodo

I-

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oxo

O2-

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hydroxo

OH-

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cyano

CN-

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sulfato

SO42-

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thiosulfato

S2O32-

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nitro

NO2-

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nitrito

ONO-

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(thiocyanato)

SCN-

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(isothiocyanato)

NCS-

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if a compound already has a greek prefix in it, but needs another to denote how many of it there are use———

bis (2)

tris (3)

tetrakis (4)

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copper

cuprate

(for it being an anion only)

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gold

aurate

(for it being an anion only)

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iron

ferrate

(for it being an anion only)

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lead

plumbate

(for it being an anion only)

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tin

stannate

(for it being an anion only)

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silver

argentate

(for it being an anion only)

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stereoisomers

cis or trans differences

or optical/ chiral differences

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linkage isomer

same ligand bonded through diff atoms

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ionization isomer

ligand and counter ion switch places

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coordination isomer

diff metal same ligands