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The bulk properties of liquids are determined by the
intermolecular forces
The molecules in a liquid are in constant motion, but since the mean free path is very short, their rate of __________ is much slower than in gases.
diffusion
In a phase diagram, the point where solid, liquids, and gases all coexist is the __________
triple point
Any time a material goes from a more ordered state to a less ordered state, the process is
endothermic
If the molecules have a(n) __________, the molecules will tend to align themselves with the positive end of one molecule near the negative end of the next.
dipole moment
Vapor pressure is a(n) __________ brought about by evaporation and condensation occurring at equal rates.
dynamic equilibrium
The freezing point of water __________ as the pressure is increased.
decreases
The molecules of a liquid are packed close together, so the __________ of a liquid is much higher than a gas.
density
The __________ is the highest temperature at which a material can exist as a liquid.
critical temperature
The __________ of a liquid is the temperature where the vapor pressure equals 1 atmosphere
normal boiling point
When a cooling curve is plotted, there is often a drop in temperature below the melting point of the material, before it starts to solidify. This initial dip is an indicator of
supercooling
Water is unusual because the __________ of solid water is less than liquid water near its melting point.
density
__________ is the resistance of a liquid to flow
Viscosity
In a(n) __________ phase, the molecules are pointed in the same direction but can slide past one another
nematic
When we are heating a liquid in the laboratory, we often add a boiling chip to the flask in order to prevent formation of a(n)__________, which might bump.
superheated liquid
Bromine is a liquid and chlorine is a gas at room temperature because the strength of __________ depends on the number of electrons and the shape of the molecule.
London dispersion forces
__________ allows insects to walk on the surface of a liquid and causes beads of liquid to form.
Surface tension
Nonpolar molecules interact with each other through __________.
London dispersion forces
In liquid acetone, (CH3)2C=O), __________ are the strongest intermolecular force.
dipole-dipole attractions
When dry ice warms up, it changes directly from a solid to a gas in a process known as __________.
sublimation
__________ are made from the combination of a small spherical anion with a large asymmetrical cation and have melting points below room temperature
Ionic liquids
Molecules in a(n) __________ liquid are held together by strong intermolecular forces, which results in a low vapor pressure.
nonvolatile
A liquid where the molecules are equally disordered in all directions is __________.
isotropic
When a material is heated above its critical temperature at a pressure above its critical pressure, the phase of the material is a(n)__________.
supercritical fluid
Liquid crystals have unusual optical properties because they can __________ with an electric field and change their orientation
interact
For compounds with hydrogen atoms bonded to nitrogen, oxygen, or fluorine, __________ are an extreme form of dipole-dipole interaction due to the large dipole moment and short distances.
hydrogen bonds
Plants rely on __________ to transport water from the roots to the leaves.
capillary action
Two liquids that form a solution for all compositions are __________ with each other.
miscible
__________ describes the solubility of a gas in a solvent based on its partial pressure.
Henry's law
If the enthalpy of solution is positive and still a solution forms, the __________ of solution must also be positive.
entropy
An anion and cation that exist together for short periods of time are __________.
ion pairs
__________ is the principle that is used when salt is spread on the roads to melt snow and ice.
Freezing-point depression
A(n) __________ solution will spontaneously crystallize if a seed crystal is added.
supersaturated
__________ occurs when water is returned to a river or lake at a higher temperature than when it was removed
Thermal pollution
The solubility of gases __________ as the temperature is increased in contrast to the solubility of most solids.
decreases
The energy to overcome the intermolecular interactions in a solute and form a solution comes from the __________ of the solute particles.
solvation
__________ are properties that depend only on the number of solute particles present in solution.
Colligative properties
A(n) __________ is a solution whose properties can be explained in terms of a simple model.
ideal solution
The __________ allows the number of particles formed when a solute dissolves in a solvent to be accounted for in determining colligative properties.
van't Hoff factor
The entropy of solution is positive because the solution is more __________ than pure solvent and solute
disordered
Components of a mixture can be purified by __________ because of differences in their solubilities in a solvent at different temperatures.
fractional crystallization
The __________ of water is one of the highest known, which explains why water will dissolve many ionic compounds.
dielectric constant
The disease sickle-cell anemia is caused by the replacement of one hydrophilic amino acid by a(n) __________ amino acid.
hydrophobic
Solutions of metals in liquid mercury are __________ and are usually solids and can be used in gold mining or dentistry.
amalgams
A(n) __________ is essentially a mixture of phospholipid molecules that form a bilayer and act to separate components
cell membrane
The __________ is the scattering of a beam of light by colloidal particles
Tyndall effect
A class of compounds called __________ was developed in order to dissolve ionic compounds in nonpolar solvents
crown ethers
Smoke and fog are examples of __________, where a liquid or solid is dispersed in a gas
aerosols
A(n) __________ is a mixture that will separate on standing and may be filtered.
suspension
When a nonvolatile solute is dissolved in a solvent, both the __________ and the freezing point of the solution are lowered.
vapor pressure
__________ allows the vapor pressure of a solution to be predicted based on the mole fraction of each component.
Raoult's law
The __________ of a solution is the number of moles of solute per kilogram of solvent.
molality
__________ uses pressure to force solvent molecules through a semipermeable membrane to purify the solvent
Reverse osmosis
Detergents and soaps spontaneously form __________ in order to minimize interactions of the nonpolar tails with water.
micelles
A molecule that contains a number of polar functional groups would be classified as __________.
hydrophilic