Section 2 chapter 4 chem

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36 Terms

1
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But could electrons have a dual wave like particle mature aswell who made this statement ?

1924 the french scientest louis de brogli

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Which he states the behaviour

Of electrons is very similar to that of an waves that was made in bhors expirements

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which the scientests knew

That any wave confined in a space can have only certain frequinces

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What did he sugest

He sugestesd thet the electron is a confined space around the atomic nucleus

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Which can mean?

That electrons exist at certain frequencies

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Briglies expirements were soon

Confirmed by expirements

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Which investegators stated

That ekectrins like light waves can be bent ir difra ted

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Diffraction means?

Its the bending of a wave as it passes through the edge of an object or through a small opening

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Other investigations

Made that the electrons beams can interfere with each other

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Interfrence?

Ocurs when waves overlap

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Which resuakts in

Increase of energy in some areas and decrease of energy in some other areas

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The wuantum theory

Assumes The proability of an electron at a specific place in the empty space surrounding the nucleus

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Quantum numbers

Specifcy the properties of atomic orbitals and the properties of electrons in the orbitals

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This three dimensional region of empty space it can be described as?

An electron cloud surrounding the nucleus

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Atomic orbitals are of?

Diffrent shapes and sizes

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Quantum number

Specify the properties of atomic orbitals and the properties of electrons in orbitals

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The principle the quantum number

symbolized by n indicates the main energy level ocupied by electrons

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Values of n

Are positeve only

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As n increase

The electrons energy snd its average distance from the nucleus increases

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More than one electron can o cant have the same amount of n?

Yes they can

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The ones that have the same n are sometimes told to be

In the same shell

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The amiunt of orbitals exist in a given shell are expressed in?

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Except at the? What exists?

First main energy level

Orbitals of different shapes known as sublevels exist for a given value of m

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Angular momentom

The nunbers of ls allowed are?

Symbolized by l indicates the shape of the orbital

Zero and all positeve integers

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How can we get the L?

N-1 the answer will consist of one number less than the energy level until last

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Depending on the value of l the orbitals are assigned letters which are?

Spdf

0-3

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There shapes?

S is spehirical p is like a dumbell and d and f are complex

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We knew sub levels are spfd so how many spdf does energy level 1 have?

It has 1 two has 2 three has 3 four has 4

1s

2s 2p

3s 3p 3d

4s 4p 4d 4f

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Atomic numbers can have the same shale but?

Diffrent orientation around the nucleus

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The magnetic quantum number. They are?

Symbolized by m indicates the orientation of an orbital around the nucleus

-l . 0 +l

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Beacuse the s has a m number of zero?

And its a supherical shape there in only way it can orientate around the nucleus

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If the l is 2(d) ghow many irbitals are there?

5 orbitals

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The 3d dimension indicates?

The location of the center of the nucleus

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The 5 diffrent d shape orbitals there differece? Each one occupies?

4 have the same shape different orientation

1 has a diffrent shape

Each one ocupies a diffrent region of space

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How do we get the number of orbitals per an energy level?

Number of electrons per s sub level?

Number of electrons per main energy level?

Use there orbitals and times by two

2 6 10 14

2xn²

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The electron has how many spin states? Which creates what?

Spin states

A single orbital can hold how many electrons? But they have to spin ? Why?

One of the two spin states

Magnetic field

Has only two posible values ½ -1/2 whcih indicates two fundamental spin states of an electron in an orbital

2 electrons but they have to spin in opposite ways

To negkect the magnetic field