Isomerism

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15 Terms

1
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what are enantiomers

optical isomers that are non-superimposable mirror images about a chiral centre

2
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what is meant by a chiral centre

a carbon atom in a molecule bonded to 4 different atoms or groups

3
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how do enantiomers differ in their interaction with plant polarised light

they rotate plane-polarised light in opposite directions

1 rotates it clockwise

other anti-clockwise

4
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what does it mean for a molecule to be optically active

has the ability to rotate the plane of polarised light due its chiral structure

5
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what is meant by the term racemic mixture

equal mixture of 2 enantiomers of a chiral compound

6
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why are racemic mixtures optically inactive

rotation caused by the 2 enantiomers cancel each other out

7
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what is optical isomerism

type of stereoisomerism-where isomers have the same structural formula but different arrangement of atoms in space

8
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how can optical isomers be distinguished

by their ability to rotate plane polarised light in opposite directions

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