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The complete combustion reaction of methane and oxygen: CH4 + 2 O2 = CO2 + 2 H2O is
a global equation behind which many elementary processes are hidden
The sequence of carbon containing intermediates involved in the oxidation of methane to CO2 is
CH4 - CH3 - CH3O - CH2O - CHO - CO - CO2
An endothermic process is a process
which absorbs heat and whose enthalpy of reaction is positive
Combustion reactions are globally
exothermic
It is possible to carry out combustion in difluorine (F2)
true
In this course, the equivalence of ratio of a mixture is given by the ratio
(quantity of fuel / quantity of oxidizer)_studied mixture / (quantity of fuel / quantity of oxidizer)_stoichiometric mixture
An oxidizing – fuel mixture with an equivalence ratio equal to 2 is
a rich mixture and a mixture with excess of fuel over stoichiometry
An Ostwald diagram
is valid for a given fuel
An equivalence ratio (or an air factor) equals to 1 allows complete combustion
false
1 kilowatt-hour (kWh)
corresponds to 3.6MJ and is an energy
What are NASA polynomials used for
calculate the thermodynamic properties of a species
In the NASA polynomial formalism, the first seven coefficients are used to calculate the thermodynamic properties of species
at high temperature
Consider the reaction between one mole of H2 and one mole of O2. The right expression of the complete reaction of combustion is:
H2 + O2 = H2O + 0.5 O2
An adiabatic flame temperature is calculated at
constant pressure
When calculating an adiabatic flame temperature in air
we need the Cp of the products and the nitrogen, and the enthalpies of formation of reactants and products
The adiabatic explosion temperature is
higher than flame adiabatic temperature
The order of magnitude of a flame temperature in air is
2000 - 2500 K
When a combustion reaction is carried out in pure oxygen
the adiabatic flame temperature is higher than in air
For lean mixtures (when the equivalence ratio is less than 1) the decrease in temperature observed is due to
the effect of dilution by atmospheric nitrogen and an excess of oxygen
Why does the calculation by hand of the adiabatic flame temperature of a fuel in air give a different result from the Gaseq software
because the reaction is considered to be complete whereas it is not true and because one can consider that N2 is inert
Gaseq software uses thermodynamic properties stored as NASA polynomials in a text file
true
In Gaseq, the value of the adiabatic flame temperature of a fuel depends on the products considered
true
To lower the flame temperature in a process operating under oxycombustion, __________ can be introduced at the inlet of the combustion chamber
water
The enthalpy of a combustion reaction
changes little with temperature
We want to calculate the adiabatic flame temperature of one mole of methane in the presence of 2 moles of O2 in the air. The reaction to consider is
CH4 + 2 O2 + 7.52 N2 = CO2 + 2 H2O + 7.52 N2
I can carry an acetylene cylinder horizontally
false
A value of calorific power is a
energy per unit volume or mass
The HHV (high heating value) is
greater than the LHV (lower heating value)
For a fuel in the gaseous state under standard conditions, the LHV is equal to the opposite of the combustion reaction enthalpy if we consider that the reaction is ___________ and ________.
complete and total
The LHV of biogas is higher than that of natural gas
true
The effective LHV of wood
decreases with residual water content
It is better to burn wet wood than dry wood
false
The octane rating of a gasoline fuel characterizes the fuel's propensity to self-ignite
true
E10 fuel is more economically advantageous than Eurosuper fuel
false
I have a vehicle that runs on 100% ethanol fuel. I should fill it up
more often
A reaction whose enthalpy is negative
gives off heat and is an exothermic reaction
A mixture containing 4 moles of oxygen and 1 mole of methane is
a mixture with an equivalence ratio of 0.50
The adiabatic flame temperature of acetylene in O2 is calculated using
the Cp of the products
Calorific power is expressed in
J/kg and J/m³
A gasoline engine can be considered as
a closed reactor with a variable volume
The ideal thermodynamic cycle of a diesel engine consists of
two isentropic transformations, one isobaric and one isochoric
The Cp of a fuel
increases with temperature
The HHV is calculated by
LHV - latent heat of vaporisation and LHV + latent heat of condensation
For rich mixtures (when the equivalence ratio is higher than 1), the decrease in adiabatic flame temperature is due to
deficit in oxygen and an incomplete reaction
Which of these units correspond to energies
J and KWh