Isomers

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7 Terms

1
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Linkage Isomer

Requires the presence of an ambidentate ligand
(2 different atoms can bond to the metal but only one at a time) (not bidentate)

<p>Requires the presence of an ambidentate ligand<br>(2 different atoms can bond to the metal but only one at a time) (not bidentate)</p>
2
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Cis

2 of the same ligand are adjacent (90°)

<p>2 of the same ligand are adjacent (90°)</p>
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Trans

2 of the same ligand are opposite (180°)

<p>2 of the same ligand are opposite (180°)</p>
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Fac (Facial)

3 groups occupy the trigonal face of an octahedral (All 3 ligands cis to each other at 90°)

<p>3 groups occupy the trigonal face of an octahedral (All 3 ligands cis to each other at 90°)</p>
5
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Mer (Meridional)

3 ligands in the same plane of a t-arrangement (2 ligands cis at 90°, 1 ligand trans at 180°)

<p>3 ligands in the same plane of a t-arrangement (2 ligands cis at 90°, 1 ligand trans at 180°)</p>
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Cis-Bis Chelates

Octahedral with 2 bidentate ligands and 2 monodentate ligands that are cis (can’t be trans because not optically active)

<p>Octahedral with 2 bidentate ligands and 2 monodentate ligands that are cis (can’t be trans because not optically active)</p>
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Tris Chelates

Octahedral with 3 bidentate ligands

<p>Octahedral with 3 bidentate ligands</p>