gen chem chapter 11 MCAT

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10 Terms

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oxidation

the loss of electrons

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reduction

gain of electrons

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oxidizing agents

facilitates the oxidation of another compound and is itself reduced in the process

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reducing agents

facilitates the reduction of another compound and is itself oxidized in the process

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complete ionic equation

accounts for all of the ions present in a reaction.

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net ionic equations

ignore spectator ions to focus only on the species that actually participate in the reaction

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disproportionation/ dismutation

type of redox reaction in which one element is both oxidized and reduced forming at least two molecules containing the element with different oxidation states

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potentiometric titration

a form of redox titration in which a voltmeter or external cell measures the electromotive force (emf) of a solution. No indicator is used the the equivalence point is determined by a sharp change in voltage

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Pauli exclusion principle

states that no two electrons in an atom can possess the same set of four quantum numbers. This is due to the fact that electrons have a negative charge and therefore repel each other; therefore, they must position themselves to minimize this repulsion energy.

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Aufbau principle,

literally the building-up principle, is a scheme for assigning electrons to specific orbitals to produce an electronic configuration for a given atom. It is related, in part, to the fact that no two atomic electrons share the same set of four quantum numbers, but does not explicitly state this requirement.