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intramolecular force
a force that exists within a molecule
bond
name of intramolecular force
intermolecular force
forces of attraction BETWEEN molecules
London dispersion forces
attractions of protons in one molecule or atom temporarily attracting electrons in another molecule or atom
size (larger = more ldfs)
shape (long/skinny = more ldfs because of surface area)
what are LDFs determined by?
all of them
which substances have LDFs?
temporary dipole
an intermolecular force between nonpolar molecules caused by the presence of temporary dipoles within the molecules
(the gif is a good representation of this…)
permanent dipole
permanent separation of electrical charge in a molecule due to unequal distributions of bonding and/or lone pairs of electrons
dipole-dipole forces
attraction between positive part of one polar molecule to the negative part of another molecule
strong type of intermolecular dipole-dipole attraction. Occurs between hydrogen and F, O or N
Hydrogen bonding
dipole-induced dipole forces
a type of intermolecular interaction that occurs between a polar molecule (which has a permanent dipole) and a nonpolar molecule (which does not have a permanent dipole)
ion-dipole forces
(when something that makes ions dissolves in something polar) attractive forces between an ion and a polar molecule
gas
weak IMFs
solid
strong IMFs
boiling point
More polar the molecule, the higher the…
London, dipole
If molecular weight is about the same, they have about the same # of protons and electrons (___ forces are about the same) - but _ forces can be different