Alkanes

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10 Terms

1
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name of substance that paraffin is obtained

name of process used to obtain paraffin

CRUDE OIL or PETROLEUM

Fractional distillation

2
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incomplete combustion

C12H26 + 12.5O2 —> 12CO + 13H2O

3
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explain how oxides of nitrogen are formed

nitrogen and O2 from air react/ combine

at high temperatures

4
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equation how nitrogen monoxide in the air is converted into nitrogen dioxide

2NO + O2 —> 2NO2

5
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equation to show how nitrogen dioxide reacts with oxygen and water to form nitric acid

4NO2 + O2 + 2H2O —> 4HNO3

6
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cracking catalyst

zeolite

7
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Why the m.p of dodecane is higher than the m.p of straight chain alkane produced by cracking dodecane

larger molecules ; larger SA ;

STRONGER VDW forces of attraction in between molecules

8
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reagent to identify isomers

BROMINE WATER

alkenes = colourless

alkanes = orange/ brown

9
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why bromoalkane is formed as a minor product

Reaction goes via INTERMEDIATE CARBOCATIONS

TERTIARY CARBOCATION is MORE STABLE

10
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how distinguish between aldehyde (-c=o-h)

and ketone (=o)

ketone =

tollens reagent - no reaction

fehlings solution - no reaction

acidified potassium dichromate - no reaction

aldehyde =

tollens reagent - silver mirror

fehlings solution - blue —> brick red ppt

acidified potassium dichromate = orange —> green