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B. Their negative effect on the natural environment. The information indicates that refrigerants manufactured a few decades ago are now banned due to their negative environmental impact.
False. While contained within a system, refrigerants are stable, are not pollutants, and produce no harmful effects.
B. Willfully purging or venting certain refrigerants to the atmosphere. It is established by regulations that it is illegal to knowingly release certain refrigerants to the atmosphere.
B. Gloves and goggles. One of the safety guidelines advises wearing gloves and goggles any time refrigerant is transferred between containers.
C. Department of Transportation (DOT)-approved containers. The guidelines state to transfer refrigerants only into DOT-approved containers.
B. Always follow retrofit guidelines. A key piece of advice for retrofitting is to always follow the established guidelines.
B. R-410A operates at higher pressures that R-22 equipment cannot handle. Service equipment for R-410A must be rated to handle its higher operating pressures.
B. Room sensors and alarms. ASHRAE Standard 15 requires the use of room sensors and alarms to detect R-123 refrigerant leaks.
B. To the outdoors. Pressure relief devices should be vented to the outdoors to prevent the buildup of excessive system pressures.
B. The presence of air or other noncondensables in the tank. A high-pressure reading in a recovery tank signals the presence of air or other noncondensables.
C. More than 90%. Stratospheric ozone accounts for more than 90% of the earth’s total ozone.
B. To shelter the earth from UV-B radiation. Stratospheric ozone shelters the earth from UV-B radiation, which is essential for human health.
C. Man-made chemicals containing chlorine. Stratospheric ozone is rapidly being depleted by man-made chemicals containing chlorine, including CFC and HCFC refrigerants.
A. About 10%. The troposphere holds only about 10% of the total ozone.
B. Smog. A popular term for tropospheric ozone pollution is smog.
B. By acting on chemicals present in the troposphere. Sunlight acting on chemicals in the troposphere creates bad ozone.
C. Three oxygen atoms (O3). Ozone is a form of oxygen gas that is made up of three oxygen atoms.
B. Between 7 and 30 miles. Stratospheric ozone is found in a shell 7 to 30 miles above the earth.
True. The sun’s ultraviolet radiation breaks down the ozone (O3) molecule into a standard oxygen (O2) molecule and a free oxygen (O) atom.
B. Plant photosynthesis and bonding of oxygen molecules with free oxygen atoms. At the same time, more ozone is produced through plant photosynthesis and the bonding of standard oxygen (O2) molecules with free oxygen (O) atoms.
D. A chlorine atom (Cl). Once in the stratosphere, ultraviolet radiation will separate a chlorine atom (Cl) from a CFC or HCFC molecule.
C. Up to 100,000. One chlorine atom (Cl) can destroy up to 100,000 ozone molecules.
C. The United Nations Environment Programme (UNEP) Montreal Protocol. Under the United Nations Environment Programme (UNEP) Montreal Protocol, an index called the ozone depletion potential (ODP) has been used for regulatory purposes.
B. Increased skin cancers and cataracts. The depleted ozone molecules in the stratosphere let more UV-B radiation reach the earth, causing an increase in skin cancers and cataracts in humans and animals.
C. Decrease in plant and marine life. Increased UV-B radiation can also lead to a decrease in plant and marine life.
B. Heat generated when stratospheric ozone intercepts ultraviolet light. When stratospheric ozone intercepts ultraviolet light, heat is generated, which is the force behind stratospheric winds affecting weather patterns.
B. The greenhouse effect. This warming process, caused by the atmosphere’s absorption of the heat energy radiated from the earth’s surface, is called the greenhouse effect, or global warming.
B. CFCs, HCFCs, HFCs, carbon dioxide, and water vapor. Naturally occurring gases and tropospheric pollutants like CFCs, HCFCs, and HFCs—as well as carbon dioxide, water vapor, and many other chemicals—are referred to as greenhouse gases.
B. 1. Carbon dioxide (CO2) has a baseline GWP of 1.
C. 25%. Human needs have resulted in an increase in the amount of carbon dioxide in the atmosphere by 25% in excess of its usual concentration.
C. Combustion of fossil fuels. Most of this increase is due to the combustion of fossil fuels, a by-product of electricity generation required by the modern world.
D. More than half. In fact, more than half of the electricity generated is used to power refrigeration and air-conditioning equipment.
A. By being improperly charged, leading to inefficiency and longer run times. Even refrigeration or air-conditioning systems with relatively small refrigerant charges that never leak may have a great impact on global warming if the equipment is improperly charged, leading to inefficiency and longer run times.
C. Total Equivalent Warming Impact (TEWI). The total equivalent warming impact (TEWI) takes into consideration both the direct and indirect global warming effects of refrigerants.
B. HCFCs and HFCs. Using HFC and HCFC refrigerants in the place of CFCs will also reduce the TEWI.
B. Methane and ethane. Most refrigerants are made from two molecules, methane and ethane.
C. Pure hydrocarbons. These two molecules contain hydrogen (H) and carbon (C) and are referred to as pure hydrocarbons (HCs).
B. Their flammability. Pure hydrocarbons were at one time considered good refrigerants, but because of their flammability they were not used after the 1930s to any large degree.
C. NH3. Ammonia contains only nitrogen and hydrogen (NH3).
C. When hydrogen atoms are removed from methane or ethane and replaced with halogens like chlorine or fluorine. Any time some of the hydrogen atoms are removed from either the methane or ethane molecule and replaced with halogens such as chlorine or fluorine, the new molecule is said to be halogenated.
B. Chlorine, fluorine, and carbon. CFCs contain chlorine, fluorine, and carbon.
B. Their molecules are not destroyed before they reach the stratosphere. CFCs are considered the most damaging to stratospheric ozone because their molecules are not destroyed before they reach the stratosphere.
B. July 1, 1992. It became illegal to intentionally vent CFC refrigerants into the atmosphere on July 1, 1992.
C. R-12. One important refrigerant is R-12, because it is commonly used for residential and light commercial refrigeration and for centrifugal chillers in some commercial buildings.
A. R-11. R-11 is used for many centrifugal chillers in office buildings and also as an industrial solvent to clean parts.
C. Hydrogen, chlorine, fluorine, and carbon. HCFCs contain hydrogen, chlorine, fluorine, and carbon.
B. They are less stable in the atmosphere and tend to break down before reacting with stratospheric ozone. Although these refrigerants have much less potential for ozone depletion because they tend to break down in the atmosphere, releasing the chlorine before it reaches and reacts with the ozone in the stratosphere.
C. 2030. The HCFC group is scheduled for a total phase-out by the year 2030.
B. July 1, 1992. As with CFCs, it became illegal to intentionally vent HCFC refrigerants into the atmosphere on July 1, 1992.
B. 2010. HCFC-22 (R-22) has an earlier phaseout date of 2010 for new equipment.
B. No production and no importing of the refrigerants. Total phaseout means no production and no importing of the refrigerants.
B. The Montreal Protocol. The Montreal Protocol was modified in 2007 and the HCFC phaseout schedule was accelerated.
C. 75%. In 2007, reduction of HCFC production was accelerated from 65% to 75% from the baseline production year of 1989.
C. Hydrogen, fluorine, and carbon. The third group of refrigerants is the HFC group, which contains hydrogen, fluorine, and carbon atoms.
False. HFC molecules contain no chlorine atoms and will not deplete the earth’s protective ozone layer.
C. November 15, 1995. On November 15, 1995, it became unlawful to intentionally vent HFC refrigerants into the atmosphere.
B. R-134a is not compatible with any oil left in an R-12 system or some R-12 system materials. The original plan to replace R-12 with R-134a is complicated because R-134a is not compatible with any oil left in an R-12 system and also not compatible with some of the materials used to construct R-12 systems.
B. A complete oil change, checking system gaskets, and contacting the manufacturer for compressor material compatibility. Retrofitting an R-12 system to R-134a requires a complete oil change, removal of residual oil, checking all system gaskets for compatibility, and contacting the manufacturer for compressor material compatibility.
C. Hydrogen, fluorine, and carbon. Hydrofluoro-olefin (HFO) refrigerants are also composed of hydrogen, fluorine, and carbon atoms.
C. HFOs have carbon atoms linked by a double bond, while HFCs have single bonds. HFOs are distinguished from HFCs by being derivatives of olefins (which have carbon atoms linked by a double bond) rather than alkanes (which have single bonds between carbon atoms).
C. Zero ODP, Extremely low GWP. Both HFO-1234yf and HFO-1234ze have a zero ODP with extremely low global warming potentials (GWPs).
C. A2L. The safety rating for refrigerants such as HFO-1234yf and HFO-1234ze, which are slightly flammable and have low toxicities, is A2L.
B. HFO-1234yf. HFO-1234yf is a low GWP replacement for R-134a intended for use in mobile air-conditioning (MAC) systems in the automotive industry.
B. HFO-1234ze. HFO-1234ze is intended to replace R-410A in residential and light commercial air-conditioning and heat pump applications while offering a 75% reduction in GWP.
C. Polyol ester (POE) oils. HFOs are miscible in polyol ester (POE) oils.
D. A3. HC refrigerants are classified by ASHRAE in the A3 safety group, meaning they are highly flammable.
A. Hydrogen and carbon. Pure HC refrigerants have no chlorine or fluorine in their molecules as they contain only hydrogen and carbon.
D. Zero. Since HCs do not contain any chlorine, they have a zero ODP.
B. 3.0. R-290 (propane) and R-600a (isobutane) both have a GWP of 3.0.
C. Ammonia. The most efficient and environmentally safe refrigerants that exist in the world today are all natural refrigerants, which include hydrocarbons, ammonia, air, water, and carbon dioxide.
C. EPA’s Significant New Alternative Policy (SNAP) program, only in new equipment, in limited conditions, and with limited charge amounts. In the United States, only some HC refrigerants have been approved by the EPA under its Significant New Alternative Policy (SNAP) program, for use only in new equipment, in limited conditions, and with limited refrigerant charge amounts because of their high flammability.
C. To assist in oil return to the compressor. For many years, small percentages of HC refrigerants have been used in many HCFC- and HFC-based refrigerant blends in the United States to assist in oil return to the compressor.
C. 5.3 ounces (150 grams). R-290 (propane) can be used in household refrigerators, freezers, combination refrigerators and freezers, vending machines, and room air-conditioning units as long as the refrigerant charge does not exceed 5.3 ounces (150 grams).
False. Retrofitting equipment containing HC refrigerants and other flammable refrigerants is not allowed in the United States.
C. Red. All refrigerant piping through which the refrigerator or freezer is serviced must be colored red.
B. PMS #185. This red must be Pantone Matching System (PMS) #185.
B. At least 1 inch or 2.54 centimeters. The red color must be present on the refrigerant process tubing and service ports or wherever a service technician may puncture the tubing for service purposes, extending at least 1 inch or 2.54 centimeters from the compressor and at least 1 inch on each side of the process tubes or service ports.
C. Immediately stop work and notify appropriate authorities, as an unauthorized retrofit may have occurred. If the data from both the cabinet and compressor or condensing unit do not match, an unauthorized retrofit may have been done, and an immediate stoppage of work should follow, with appropriate authorities notified.
C. Make sure the compressor’s terminal covers are in place. One of the safety precautions to prevent terminal venting is to make sure the compressor’s terminal covers are in place before energizing the compressor.
B. A short in the motor windings at the fusite terminals or a weak spot in the windings, potentially damaging the compressor. Energizing the compressor when under a deep vacuum can cause a short in the motor windings at the fusite terminals or at a weak spot in the windings, which may damage the compressor.
B. They are excellent dielectrics. Both oil and refrigerant are excellent dielectrics, meaning they are good electrical insulators.
C. Lower Exposure Limit. The lower exposure limit (LEL) of a gas is the lowest concentration of the gas in air capable of producing a flash or fire in the presence of an ignition source.
B. 2.1%. Propane (R-290) has an LEL of 2.1% concentration in air.
C. 8.5%. Isobutane (R-600a) has a UEL of 8.5% concentration in air.
D. All of the above. Sparks from a vacuum pump switch, pressure switch, contactors, electronic leak detector, halide torch, light switch, defrost timers, or thermostats can cause explosions when exposed to the proper concentrations of HC gas and air.
C. Before disconnecting power or unplugging anything. Never disconnect power or unplug anything or begin a service procedure before checking for flammable refrigerants in the area with a combustible gas leak detector or monitor.
B. Monitor, Ventilate, Eliminate. Service technicians must: Monitor the area for combustible gasses. Ventilate the area to get rid of any combustible gasses. Eliminate any sources of ignition.
C. Non-ignitable types such as ultrasonic detectors, liquid solutions, or ultraviolet additives. Always use non-ignitable type leak detectors for HC gases such as ultrasonic detectors, liquid solutions, or ultraviolet additives.
C. Spark-proof tools, like brass tools. Service technicians should use spark-proof tools, and many brass tools are spark-proof.
False. Never use a torch to remove refrigerant components; always use tubing cutters.
B. The vehicle must be labeled to indicate it is carrying flammable gas. The vehicle must be labeled to let the general public know it is carrying a flammable gas.
B. In the upright position. HC cylinders must be transported in the upright position.
B. They must be stored away from any ignition source. Store cylinders away from any ignition source.
B. The first digit from the right is the number of fluorine atoms. The first digit from the right is the number of fluorine atoms.
C. One more than the number of hydrogen atoms. The second digit from the right is one more than the number of hydrogen atoms.
D. The number of carbon atoms minus one, with zero indicating one carbon atom. The third digit from the right is one less than the number of carbon atoms, and if this number is zero, there is one carbon atom and the refrigerant is methane-based.
B. 2. For R-123, the third number from the right is 1. According to the rule, this is one less than the number of carbon atoms, so there are 1 + 1 = 2 carbon atoms.
B. 1. For R-12, the third number from the right is 0. This indicates one less than the number of carbon atoms, so 0 + 1 = 1 carbon atom, meaning it is methane-based.
B. How symmetrical the molecular arrangement is, indicating isomers. The small letters “a, b, c, d, . . .” at the end of the numbering system represent how symmetrical the molecular arrangement is, indicating isomers of one another.
False. R-134a and R-134 are completely different refrigerants with completely different properties, despite having the same number of atoms of the same elements, differing only in arrangement (isomers).