Oxidation Numbers and OILRIG Principles in Chemistry

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12 Terms

1
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What is the oxidation number of any uncombined element?

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2
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How does the oxidation number of a monatomic ion relate to its charge?

It equals the charge on the ion.

3
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What oxidation number is assigned to the more-electronegative element in a binary compound?

The number equal to the charge it would have if it were an ion.

4
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What is the oxidation number of fluorine in a compound?

Always -1.

5
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What is the oxidation number of oxygen in most compounds?

-2, unless combined with fluorine (when it is +2) or in a peroxide (when it is -1).

Na2O2



H2O2



K2O2

6
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What is the typical oxidation state of hydrogen in its compounds?

+1, unless combined with a metal, in which case it is -1.

7
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What are the oxidation numbers for elements in groups 1 and 2, and aluminum?

+1 for group 1, +2 for group 2, and +3 for aluminum.

8
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What is the sum of the oxidation numbers in a neutral compound?

0

9
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What does the sum of the oxidation numbers in a polyatomic ion equal?

The charge of the ion.

10
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What does OILRIG stand for in terms of oxidation and reduction?

Oxidation Is Loss, Reduction Is Gain.

11
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What does oxidation involve in terms of oxidation number?

A gain in oxidation number.

12
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What does reduction involve in terms of oxidation number?

A loss in oxidation number.