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hexane
non-polar
benzene
non-polar
toluene
non-polar
What’s a polar protic solvent?
Has -OH or -NH grp - highly polar
able to form H bonds
What’s a polar aprotic solvent?
has bonds like C=O or S=O
medium polarity
Which solvent is preferred for SN1, and why?
Polar Protic
polar: allows charges to dissociate to stabilise carbocation intermediate
protic: stabilise anion via H-bonding
Which solvent is preferred for SN2, and why?
Polar Aprotic
aprotic: stabilises Nu w/o stabilising the substrate → increases Nu’s reactivityDef
Nucleophilicity
Ability of a Nu to displace a LG in a SN reaction