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kinetic molecular theory
volume of gas is negligible
ignore all attractive/repulsive forces
collisions are random and elastic (100% energy transfer)
KE is proportional to temp in K
IntraMF
attractive forces within molecules; bonds
InterMFs
attractive forces between molecules
Ion dipole forces
strong attraction between ion and a polar molecule
strongest IMF
dipole - dipole forces
two polar molecules attracted to each other
medium strength
dipole induced dipole
polar molecule pushes e- in a nonpolar creating a dipole
pretty weak
(london) dispersion forces
chance that electrons in an atom become unevenly distributed
this creates a dipole moment giving a side of an atom a partial - charge
this is attracted to the nucleus of another atom. can induce a dipole.
the larger the atom the higher the chance for dispersion to occur
dispersion is in everything
polarizabiltiy - follows the same trend as atomic radius
only IMF that affects non-polar and noble gasses
Hydrogen bonding
very strong dipole-dipole fore between an H atom and a very polar Bond
only occurs with H’s bonded to N, O, F
These bonds have high EN and the atoms are small so they can get closer together