Electronic Structure of Atoms

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What is the Heisenberg's uncertainty principle?

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It states that it is impossible to know both the exact position and momentum of an electron simultaneously.

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What is a photon?

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A photon is a quantized packet of light energy.

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These flashcards cover key concepts in the electronic structure of atoms as described in the lecture notes.

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12 Terms

1
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What is the Heisenberg's uncertainty principle?

It states that it is impossible to know both the exact position and momentum of an electron simultaneously.

2
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What is a photon?

A photon is a quantized packet of light energy.

3
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What does the Bohr model of an atom suggest about electron orbits?

Electrons move in certain allowed orbits around the nucleus at specific energy levels.

4
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What is the principal quantum number (n)?

It indicates the size and energy of an orbital, taking positive integral values (1, 2, 3, …).

5
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Define the wave function in quantum mechanics.

Mathematical functions that describe the electron in an atom and whose square gives the probability density.

6
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What are atomic orbitals?

Regions in an atom where electrons are likely to be found, defined by quantum numbers.

7
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What is the Pauli exclusion principle?

No two electrons in an atom can have the same set of four quantum numbers.

8
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What is Hund’s rule?

Electrons will occupy degenerate orbitals singly with the same spin before pairing up.

9
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What is electron configuration?

The distribution of electrons among various orbitals in an atom.

10
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What characterizes a many-electron atom compared to a hydrogen atom?

The energy levels are altered by electron-electron repulsion, leading to distinct energy levels for different orbitals.

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What are the shapes of s, p, and d orbitals?

S orbitals are spherical, p orbitals are dumbbell-shaped, and d orbitals have more complex shapes with lobes.

12
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What is the relationship between an atom's electron configuration and its position in the periodic table?

Elements in the same group have similar valence electron configurations.