buffer solutions

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Last updated 3:45 AM on 9/5/26
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10 Terms

1
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Buffer solution definition

Solutions that are able to resist a change in pH when small amounts of acid or base are added.

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Composition of a buffer

A weak conjugate acid-base pair that forms a reversible reaction to counteract pH changes.

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Optimal buffer conditions

High concentration and equimolar concentrations of the weak conjugate acid-base pair.

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Why strong acids/bases cannot form buffers

They fully ionise or dissociate in solution

5
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CH3COOH/NaCH3COO vs HCl/NaCl buffers

CH3COOH is a weak acid with a reversible reaction; HCl is a strong acid reacting in only one direction.

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Buffering capacity definition

The amount of acid or base which can be added to a buffer before the pH will significantly change.

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Factors determining buffering capacity

The magnitude of the concentrations of the acid and conjugate base

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Effect of non-similar buffer concentrations

A buffer with dissimilar concentrations will buffer better in one direction than the other.

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Equation for buffer preparation using CH3COOH and KOH

CH3COOH(aq) + OH-(aq) ⇌ CH3COO-(aq) + H2O(l)

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Preparation method from 1 mol L-1 ethanoic acid and 0.5 mol L-1 KOH

Add equal volumes; KOH reacts with half the moles of ethanoic acid