Carbohydrates and Lipids – Key Vocabulary

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A comprehensive set of vocabulary flashcards covering the structures, functions, and key terms related to carbohydrates and lipids, as discussed in the lecture notes.

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50 Terms

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Carbohydrate

Carbon-based molecule with formula (CH2O)n; functions in cell structure, identity, and energy storage.

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Monosaccharide

Single sugar unit that serves as a monomer for larger carbohydrates.

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Oligosaccharide

Short carbohydrate polymer composed of a few monosaccharides.

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Polysaccharide

Large carbohydrate polymer made of many monosaccharide monomers.

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(CH2O)n

General chemical formula for most carbohydrates; n indicates number of carbon-hydrate groups.

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Carbonyl group

Functional group (C=O) whose position distinguishes aldoses (end) from ketoses (middle).

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Hydroxyl group

-OH functional group that participates in glycosidic bond formation and hydrogen bonding.

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Aldose

Monosaccharide with the carbonyl group at the end of the carbon chain.

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Ketose

Monosaccharide with the carbonyl group within the carbon chain.

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Triose

Monosaccharide containing three carbon atoms.

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Pentose

Monosaccharide containing five carbon atoms.

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Hexose

Monosaccharide containing six carbon atoms.

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Ring form

Cyclic structure adopted by most sugars in aqueous solution.

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Disaccharide

Carbohydrate formed when two monosaccharides are linked by a glycosidic bond.

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Condensation reaction

Reaction in which two molecules join, producing water; forms glycosidic bonds in carbohydrates.

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Hydrolysis reaction

Reaction that breaks covalent bonds by adding water; splits glycosidic linkages.

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Glycosidic linkage

Covalent bond formed between two sugars via condensation of hydroxyl groups.

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α-1,4-glycosidic linkage

Bond connecting C-1 of one α-glucose to C-4 of another; common in starch and glycogen.

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β-1,4-glycosidic linkage

Bond connecting C-1 of one β-sugar to C-4 of another; found in cellulose, chitin, peptidoglycan.

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Starch

Plant storage polysaccharide composed of amylose (unbranched) and amylopectin (branched).

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Amylose

Unbranched component of starch with α-1,4 linkages forming a helix.

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Amylopectin

Branched component of starch containing occasional α-1,6 linkages.

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Glycogen

Highly branched animal storage polysaccharide with many α-1,6 linkages.

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Cellulose

Structural polysaccharide of plant cell walls composed of β-1,4-linked glucose strands hydrogen-bonded in parallel.

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Chitin

Structural polysaccharide of fungal cell walls and arthropod exoskeletons made of β-1,4-linked N-acetylglucosamine.

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Peptidoglycan

Bacterial cell-wall polysaccharide of alternating N-acetylmuramic acid and N-acetylglucosamine cross-linked by peptides.

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N-acetylglucosamine (NAG)

Modified monosaccharide forming part of chitin and peptidoglycan.

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N-acetylmuramic acid (NAM)

Modified monosaccharide unique to peptidoglycan that carries a peptide chain.

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Amino group

-NH2 functional group that acts as a base by accepting a proton.

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Carboxyl group

-COOH functional group that acts as an acid by donating a proton.

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Phosphate group

-PO4 functional group storing large amounts of chemical energy when linked together.

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Sulfhydryl group

-SH functional group that can form disulfide bonds in proteins.

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Lipid

Carbon-containing compound that is largely nonpolar and insoluble in water.

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Hydrocarbon

Molecule consisting only of carbon and hydrogen; nonpolar and hydrophobic.

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Isoprenoid

Branched hydrocarbon built from isoprene units; functions as pigments, vitamins, and lipid precursors.

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Fatty acid

Unbranched hydrocarbon chain (14–20 C) with terminal carboxyl group.

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Saturated fatty acid

Fatty acid with only single C–C bonds; straight chain packs tightly.

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Unsaturated fatty acid

Fatty acid containing one or more C=C double bonds, creating kinks in the chain.

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Polyunsaturated fatty acid

Fatty acid with multiple double bonds in its hydrocarbon chain.

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Steroid

Lipid family characterized by a bulky four-ring structure; includes cholesterol and sex hormones.

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Cholesterol

Steroid component of animal plasma membranes that modulates fluidity.

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Fat (Triacylglycerol)

Lipid consisting of three fatty acids linked to glycerol; primary energy storage molecule.

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Glycerol

Three-carbon alcohol that forms the backbone of fats and phospholipids.

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Ester linkage

Bond joining glycerol’s hydroxyl to a fatty acid’s carboxyl group in fats and phospholipids.

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Phospholipid

Lipid with glycerol bonded to a phosphate group and two hydrophobic tails; main component of cell membranes.

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Hydrophilic head

Polar, water-loving region of a phospholipid composed of glycerol, phosphate, and charged group.

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Hydrophobic tail

Nonpolar fatty acid or isoprenoid chains of a phospholipid that avoid water.

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Plasma membrane

Selective barrier formed by a phospholipid bilayer that separates the cell from its environment.

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Selective barrier

Property of membranes that allows entry of needed substances while excluding harmful ones.

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Energy storage (in lipids)

Function of fats which contain numerous high-energy C–C and C–H bonds, storing roughly twice the energy of carbohydrates.