Enthalpy change definitions

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11 Terms

1

Enthalpy of formation (delta fH)

Enthalpy change when one mole of a substance is formed from its constituent elements with all substances in their standard states

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2

Enthalpy of combustion

Enthalpy change when one mole of a substance undergoes complete combustion in oxygen with all substances in their standard state

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3

First ionisation Enthalpy

Enthalpy change when each atom in one mole of gaseous atoms loses one electron to form one mole of gaseous +1 ions

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4

Second ionisation Enthalpy

Enthalpy change when each atom in one mole of gaseous +1 ions loses one electron to form one mole of gaseous +2 ions

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5

First electron affinity

Enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous -1 ions

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6

Second electron affinity

Enthalpy change when each atom in one mole of gaseous -1 ions gains one electron to form one mole of gaseous -2 ions

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7

Enthalpy of atomisation

Enthalpy change when one mole if gaseous atoms is produced from an element in its standard state

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8

Bond dissociation Enthalpy

Enthalpy change when one mole of covalent bonds is broken in the gaseous state, averaged over a range of compounds

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9

Lattice Enthalpy

Enthalpy change when one mole of a solid ionic compound is broken apart into its constituent ions in the gaseous phase

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10

Enthalpy of vaporisation

Enthalpy change when one mole of a liquid is turned into a gas

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