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Coal Combustion Pollutants
Releases CO
2
, SO
2
, toxic metals (mercury), and particulate matter (PM).
Fossil Fuel Combustion Products
Nitrogen oxides (NO
x
), carbon monoxide (CO), hydrocarbons, and particulate matter.
Primary Source of SO
2
The burning of fossil fuels, specifically diesel fuels and coal.
Environmental Impact of NO
x
Leads to the production of ozone, formation of photochemical smog, and conversion into nitric acid (acid rain).
Clean Air Act & Lead
The EPA regulated lead in fuels, leading to a dramatic decrease in atmospheric lead levels.
7.2 Photochemical Smog
Front
Back
Photochemical Smog Recipe
Nitrogen Oxides (NO
x
)+VOCs+Heat+Sunlight.
VOCs (Volatile Organic Compounds)
Carbon-based molecules (like formaldehyde or gasoline) that evaporate or sublimate at room temperature.
Natural Source of VOCs
Certain species of trees and plants.
Smog Formation Timeline
NO
x
peaks in the morning (traffic); Ozone (O
3
) peaks in the afternoon/summer (high sun intensity).
Why Smog is Urban
High concentrations of motor vehicles provide the necessary NO
x
and hydrocarbons.
Health Effects of Smog
Respiratory problems (asthma, bronchitis) and eye irritation.
Reduction Strategies
Reducing emissions of NO
x
(catalytic converters) and VOCs (pump vapor recovery, low-VOC paints).