ORGANIC CHEMISTRY FINALS

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Hydrocarbons

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Description and Tags

exp 12, 13, 14, 15, 16, 18, 19

372 Terms

1

Hydrocarbons

Organic compounds that are made out of carbon and hydrogen only

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2

Flammability

The property of hydrocarbons that allows them to be used mainly for fuel

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3

Non-polar

The polarity of hydrocarbons

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4

106

The number of the estimated potential combination for carbon chain/ring

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5

Saturated hydrocarbons

Classification of hydrocarbons in which the carbons are bonded with single bonds

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6

Alkanes

These are organic compounds that are bonded with single bonds

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7

Unsaturated hydrocarbons

Classification of hydrocarbons in which the carbons are bonded with double or triple bonds

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8

Alkenes

These are organic compounds that are bonded with double bonds

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9

Alkynes

These are organic compounds that are bonded with triple bonds

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10

Sigma bond

A strong type of bond

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11

Pi bond

a weak type of bond

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12

Unsaturated hydrocarbons

Which is more reactive, saturated or unsaturated hydrocarbons?

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13

Open-chain hydrocarbons

A classification of hydrocarbons in which the compounds are arranged in acyclic, linear, straight, or branched structures

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14

closed-chain hydrocarbons

A classification of hydrocarbons in which the compounds are arranged in cyclic, ring, alipathic, or aromatic structures

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15

Paraffins

Other name for alkanes

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16

sp3

hybridization of alkanes

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17

Olefins

Other name for alkenes

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18

sp2

hybridization for alkenes

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19

sp

hybridization for alkynes

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20

Alkanes

Contains 1 sigma bond

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21

Alkenes

Contains 1 sigma bond and 1 pi bond

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22

Alkynes

Contains 1 sigma bond and 2 pi bonds

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23

CnH2n+2

General formula for alkanes

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24

CnH2n

general formula for alkenes

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25

CnH2n-2

General formula for alkynes

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26

IUPAC Nomenclature

The system used in naming chemical compounds

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27

meth

suffix for 1

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28

eth

suffix for 2

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29

prop

suffix for 3

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30

but

suffix for 4

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31

pent

suffix for 5

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32

hex

suffix for 6

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33

hept

suffix for 7

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34

oct

suffix for 8

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35

non

suffix for 9

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36

dec

suffix for 10

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37

Aromatic hydrocarbons

These are cyclic hydrocarbons with delocalized pi electrons between carbon atoms of ring or alternating double bonds

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38

Aromacity

The term that describes the natural characteristics of aromatic hydrocarbons

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39
  • Must be cyclic in structure

  • must be flat or planar in configuration

  • must have conjugated double bonds

  • must follow huckel’s rule of aromacity

Criteria for aromacity

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40

Huckel’s Molecular Orbital Theory

“A compound is particularly stable if all its bonding molecular orbitals are filled with paired electrons”

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41

Benzene

The most common example of an aromatic compound

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42

Benzene

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43

Acetanilide

knowt flashcard image
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44

Cyclohexane

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45

n-hexane

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46

Naphthalene

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47

Hydrocarbons - structures and chemical properties

Title of experiment 12

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48

Experiment 12

What experiment uses benzene, n-hexane, cyclohexane, acetanilide, gasoline and naphthalene as samples?

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49

gasoline

the only sample in experiment 12 that produced non-luminous flame and had no soot

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50

Luminous flame

burns bright yellow flame due to not enough oxygen

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51

Non-luminous flame

burns an almost invisible blue flame due to enough oxygen

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52

1 drop

How many drops of samples did the experiment 12 - ignition test require?

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53

Combustion reaction

A reaction in which hydrocarbons react with oxygen to produce CO2, H2O, and heat

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54

Incomplete combustion

Yellow flame, has soot, not much energy and heat produced

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55

Complete combustion

Blue flame, no soot, burns efficiently and produces hotter flame

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56

Benzene, n-hexane, cyclohexane

The samples that produced soot and luminous flame in the experiment 12 - ignition test

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57

Baeyer’s test for unsaturation

A test used to determine the presence of double and triple bonds

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58

Adolf von Baeyer

The scientist named after the test to determine the presence of double and triple bonds

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59

Sodium hydroxide

A compound used to make the potassium permanganate alkaline in Baayer’s test

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60

10 drops

How many drops of samples did the Baeyer’s test for unsaturation require?

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61

15 drops

How many drops of the alkaline potassium permanganate did the Baeyer’s test for unsaturation require?

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62

Benzene, cyclohexane, n-hexane

The samples that. produced a purple-colored solution in the exp 12, baeyer’s test

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63

Gasoline

the sample that produced a dark brown precipitate in the exp 12, baeyer’s test

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64

Brown

The color of precipitate that indicates a positive result in Baeyer’s test for unsaturation

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65

Oxidation reaction

A reaction that produces an alkane with 4 hydroxyl groups, a manganese dioxide, and a permanganate ion

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66

resist addition

aromatic compounds ___ to the pi bonds in which the ring system would be destroyed

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67

preserved

aromatic compounds readily undergo substitution in which the ring system is ___.

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68

0.67 grams

how many grams of acetanilide and naphthalene did the exp 12 - electrophilic aromatic substitution require?

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69

Glacial acetic acid

The reagent (2.5ml) that the acetanilide and naphthalene were dissolved into in the electrophilic aromatic substitution

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70

15 drops

how many drops of bromine in acetic acid solution did the electrophilic aromatic substitution require?

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71

Distilled water

What reagent was added to the solution solution in the electrophilic aromatic substitution until it turned cloudy?

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72

Alcohols

What is the title of experiment 13?

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73

Alcohols

organic compounds composed of an alipathic carbon atom with a hydroxyl functional group

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74

Hydroxyl group

the functional group of all alcohols

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75

ROH

the general formula for the hydroxyl group

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76

Length

Some properties of alcohols depend on the __ of alkyl chain attached to the hydroxyl group

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77

Primary alcohol

Classification of alcohol wherein a carbon with the OH group is attached to one other carbon atom

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78

Secondary alcohol

Classification of alcohol wherein a carbon with the OH group is attached to two other carbon atoms

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79

Tertiary alcohol

Classification of alcohol wherein a carbon with the OH group is attached to three other carbon atoms

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80

RCH2OH

General formula for primary alcohols

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81

R2CHOH

General formula for secondary alcohols

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82

R3COH

General formula for tertiary alcohols

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83

higher

Alcohols have ___ boiling points compared to hydrocarbons

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84

hydrogen bonding

The intermolecular force found between the OH that is responsible for the high boiling points and solubility of alcohols

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85

Increases

the boiling point of alcohols ___ as the number of carbon in alipathic chain increases

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86

decreases

the boiling point of alcohols ____ as the branching in alipathic carbon chain increases

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87

longer

The ___ the alkyl chain is, the lesser the alcohol becomes soluble in water

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88

Polar

Polarity of alcohols

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89

acidic

alcohols are ___ in nature because of their ability to react with active metals, forming corresponding alkoxide

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90

Primary alcohols

Of all the classifications of alcohols, which are more acidic?

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91

decreases

the acidity of alcohols ___ when an electron donating group is attached to the hydroxyl group as the electron density increases on the oxygen atom

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92

Jones test

The other name for the chromic acid test

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93

n-butyl, sec-butyl, tert-butyl

The samples used in the chromic acid test

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94

20 drops

How many drops of samples did the chromic acid test require?

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95

potassium dichromate

Along with the sulfuric acid, what reagent did the chromic acid test used?

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96

Chromic acid test

A test used to distinguish primary and secondary alcohols from tertiary alcohols

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97

Blue-green

the color of the solution that depicts a positive result in the jones test

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98

Jones reagent

A reagent that is made out of chromium oxide in sulfuric acid

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99

Lucas reagent

A reagent that is made our of zinc chloride in concentrated hydrochloric acid

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100

Ewart Jones

The scientist that the chromic acid test was named after

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