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Exam is on February 10th; ** look through book for conservation of mass and other physical laws of hydrology; Water's Properties, GHC, (fluxes and reservoirs residence time), Climate and the GHC, Precipitation, Evaporation and evapotranspiration (rates and mechanisms), infiltration, Chapters 1-4???
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What makes the state of water unique?
It can take the form of a solid, liquid, or gas
Density of water
dependent on salinity, temperature, and pressure
Compressibility of water
Nearly incompressible
The dissolving ability of water?
Very high dissolving ability
Heat capacity of water
The highest of all liquids and solids EXCEPT NH3
Surface tension of water
highest of any liquid
heat conduction of water
highest of any liquid
the boiling and freezing temperatures of water
anomalously high
Describe Water’s Molecular Structure
H2O - two hydrogen and one oxygen; covalent bonding
Describe ionic bonding
elements of opposite ends of the periodic table generally form ionic bonds
tendency to lose/gain electrons
forms a neutral compound
generally weak bonds
transfer of electrons from donor to acceptor
describe covalent bonding
form between atoms with partially filled outer orbitals
sharing of valence electrons
VERY STRONG BONDS
The definition of HYDROLOGY
The geoscience that describes and predicts the occurrence, circulation, and distribution of the water of the earth and its atmosphere
What is the Global Hydrologic Cycle?
The distribution and spatial and temporal variations of water in the global water system
What is Heat?
the measure of how many molecules in body are vibrating and how rapidly they are vibrating
What is Temperature?
the measure of how rapidly the molecules in a body are vibrating
Describe sensible heat
associated with temperature change
Describe latent heat
associated with change in state
What is heat capacity?
the temperature response of a body to the addition or loss of heat
The role of heat in hydrogen bonds
Heat breaks the hydrogen bonds and causes molecules to move (increasing temperature)
What is Fick’s Law of Diffusion?
describes the movement from high concentration to low concentration
rate of movement is proportional to the concentration gradient
describe the Global Energy Budget
a balance of inputs and outputs
input of solar shortwave energy
output of infrared and longwave (heat) radiation
Darcy’s Law (will not be applied to problems in exam 1)
determines how quickly water is flowing
What is the latitudinal effect on light penetration
the higher the latitude, the higher the incident angle
greater surface area affected
greater volume of atmosphere
more reflection
What are the factors affecting infiltration?
water input rate
surface ponding depth (potential for puddle formation)
surface hydraulic conductivity
saturation of surface pore spaces
surface slope and roughness
chemistry of soils
warm air is more or less dense than cold air
LESS DENSE
humid air is more or less dense than dry air
LESS DENSE
Warmer air can hold (more/less) water vapor than cold air
More water vapor
How is Coriolis force affected by latitude?
Coriolis force increases with latitude
The relationship between Coriolis force and velocity
No velocity = no Coriolis force
Describe the term “Monsoon”
Any seasonal reversing of wind direction
Summer monsoon causes
significant rainfall in most of Indian subcontinent and SE Asia
Winter Monsoon affects what?
Australia and SE Asia
What causes precipitation?
cooling
condensation
droplet growth
importation of water vapor
Describe Adiabatic Cooling!
as air pressure decreases on an air parcel, it expands, rises, and cools (without the addition or loss of heat)
What is dew point?
the temperature at which a parcel of air reaches saturation with respect to water vapor
Condensation is caused by…
the coalescence of water molecules
a process catalyzed by cloud condensation nuclei
Droplet growth needs..
high concentration of water droplets
aid by presence of template catalysts
Which processes induce adiabatic cooling?
convergence of air masses
thermal convection
orography
What is Orographic Uplift?
as an air mass rises above a mountain or landmass, it cools and expands;
What is Thermal Convection?
land mass is heated, air mass above land mass rises and cools at dry adiabatic rate, attains dew point, cools at wet adiabatic rate
(due to this instability, this is linked to thunderstorms)
ITCZ
the intertropical convergence zone
seasonal migration due to equatorial tilt and land/sea interactions
Define Interception
the segment of gross precipitation input that wets and adheres to aboveground objects until it is returned to the atmosphere through evaporation
Define Interception Loss
intercepted water that evaporates
Different types of interception loss?
canopy interception loss
litter interception loss
total interception loss
The amount of water intercepted is a function of:
rainfall intensity
the species, age, and density of prevailing plants and trees
the season of the year
Net rainfall can be described as
the loss via depression storage
loss to evaporation
infiltration to groundwater
Rate of Evaporation depends on:
relative vapor pressure in air and at evaporative surface
wind speed
degree of turbulent mixing
What is required before liquid water can change to vapor?
The breaking of hydrogen bonds
The energy required to break hydrogen bonds is called???
Latent heat of vaporization
equal and opposite to energy released during condensation
Define Transpiration
A physical process where water vapor escapes through open stoma (on the undersides of leaves)
Guard cells in plants are affected by:
light intensity
humidity
water content of leaf cells
leaf-air vapor pressure difference
ambient CO2
Hydraulic zones in soils
root zone
vadose zone
capillary fringe
saturated (phreatic) zone
Subsurface Geology Factors In Hydrology
porosity
water content
permeability
hydraulic conductivity
hydraulic pressure
What is Baseflow?
records the groundwater contribution to surface water flow
varies temporarily in response to precipitation, infiltration
The Rate of Evaporation is dependent on
relative vapor pressure in the air
wind speed
degree of turbulent mixing
subsurface geology factors
porosity
water content
permeability
hydraulic conductivity
hydraulic pressure
Types of stream gages
staff gage
wire weight gage
open pipe gage
gage house
What is gage height?
height of a stream surface relative to a reference datum
Why measure the gage height?
determines the volume of water moving in a stream
and determines the depth at which stream velocity is measured
What is stream discharge?
volume of water flowing through a stream channel
What is the fuel for streamflow?
Runoff
Runoff is the precipitation that remains
AFTER interception, infiltration, and depression storage
Overland flow
conveys water to stream channels
What are the streamflow components?
baseflow
interflow
channel precipitation
direct surface runoff
What is the purpose of a hydrograph?
it records the temporal and spatial integration of these contributors
Describe baseflow measurements
records the groundwater contribution to surface water flow;
varies temporarily in response to precipitation, infiltration