Orgo Unit1 things

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16 Terms

1
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sp3 hybridized atom

  • 4 sigma bonds

  • 3 sigma bonds + 1 nbep

  • 2 sigma bonds + 2 nbep

  • 1 sigma bond + 3 nbep

2
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sp2 hybridized atoms

  • 3 sigma bonds + 1 pi bond

  • 2 sigma bonds + 1 pi bond + 1 nbep

  • 1 sigma bond + 1 pi bond + 2 nbep

3
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sp hybridized atoms

  • 2 sigma bonds + 2 pi bonds

  • 1 sigma bond + 2 pi bonds + 1 nbep

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Bond angle: sp3

109.5°

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Bond angle: sp2

120°

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Bond angle: sp

180°

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Constitutional isomers

Molecules w/diff connectivity

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Conformational isomers

Same molecule rotated @ a bond

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Degree of Unsaturation

#C +1 - (#H + #x - #N)/2

x = halogens

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Formal charge

# valence e - # non-bonding e - # bonding e/2

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Linear

Sp hybrid

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Bent

Sp2 w/1 nbep

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Trigonal planar

Sp2 w/no nbep

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Trigonal pyramidal

Sp3 w/1 nbep

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Tetrahedral

Sp3 w/NO nbep

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