Organic Analysis and Alcohols

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24 Terms

1

Test for Alkenes

Shake with bromine water

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2

Positive test for Alkenes

Colourless solution

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3

Test for halogenoalkanes

Add Sodium Hydroxide (aq)

Acidify with nitric acid

Add silver nitrate

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4

Positive results for halogenoalkane test

AgCl = White

AgBr = Cream

AgI = Yellow

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5

Test for Alcohols

Add Acidified potassium dichromate solution

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6

Positive result for Alcohol test

Orange turns to green (Only with primary and secondary alcohols

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7

What is the result of a tertiary alcohol when adding acidified potassium dichromate

None

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8

Test for Aldehydes (T)

Warm with Tollens reagent

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9

What is a positive result for the Aldehyde test (T)

Silver mirror forms

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10

Aldehydes test (F)

Warm with Fehlings solution

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11

What is the positive result for the Aldehydes test (F)

Blue solution forms a red precipitate

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12

Test for Carboxylic acids

Add Sodium Hydrogen Carbonate

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13

Positive result for carboxylic acid. test

CO2 Gas is formed (Effervescence)

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14

What can primary alcohols be oxidised into

Aldehydes and then Carboxylic acids

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15

What can secondary alcohols be oxidised into

Ketones

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16

What type of alcohol cannot undergo oxidation

tertiary alcohols

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17

What is an oxidising agent of alcohols

K2Cr2O7 (Acidified potassium dichromate)

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18

What is the process for oxidation of primary alcohols

The alcohol undergoes distillation into an Aldehyde

The alcohol can then be further oxidised under reflux to produce a carboxylic acid

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19

What colour does Potassium dichromate become after being reduced

Orange → Green

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20

What are the two ways in which alcohol can be produced

Fermentation and the refining of crude oil

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21

What are the conditions necessary for an Elimination reaction in alcohols

600 C

Aluminium Oxide catalyst (Al2O3)

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22

What is Elimination also known as in alcohols

Dehydration

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23

What are the products of an elimination reaction

An Alkene and a Water molecule

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24

What is the mechanism

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