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temporary dipole
the separation of charge produced in an atom or molecule by a momentary uneven distribution of electrons; also called induced dipole
London dispersion force
an intermolecular force between atoms or molecules caused by the presence of temporary dipoles in the molecules
polarizability
the relative ease with which the electron cloud in a molecule, ion, or atom can be distorted, including a temporary dipole
hydrocarbon
an organic compound whose molecules contain only carbon and hydrogen atoms
alkane
a hydrocarbon in which each carbon atom is bonded to four other carbon or hydrogen atoms
constitutional isomer
one of a set of compounds with the same molecular formula but different connections between the atoms in their molecules; also called structural isomer
dipole-dipole interaction
an attraction between regions of polar molecules that have partial charges of opposite sign
organic compound
a molecule containing carbon atoms whose structure typically consist of carbon-carbon bonds and carbon-hydrogen bonds and may include other atoms such as oxygen, nitrogen, sulfur, phosphorus, or the halogens.
functional group
a group of atoms in an organic compound’s molecular structure that significantly imparts characteristic physical and chemical properties
carbonyl group
a functional group that consists of a carbon atom with a double bond to an oxygen atom
ketone
an organic compound that contains a carbonyl group bonded to two other carbon atoms
hydrogen bond
a strong dipole-dipole interaction which occurs between a hydrogen atom bonded to a N, O, or F, and another N, O, or F atom
hydroxyl group
a functional group that consists of an oxygen atom with a single bond to a hydrogen atom
alcohol
an organic compound whose molecular structure includes a hydroxyl group bonded to a carbon atom that is not bonded to any other functional group(s)
ether
an organic compound that contains an oxygen atom with single bonds to two carbon atoms
ion-dipole interaction
an attractive force between an ion and a molecule that has a permanent dipole
sphere of hydration
the cluster of water molecules surrounding an ion in an aqueous solution
solvent
the component of a solution for which the largest number of moles present
solute
any component in a solution other than the solvent
solubility
the maximum quantity of a substance that can dissolve in a given volume of solution
miscible
capable of being mixed in any proportion without reacting chemically
dipole-induced dipole interaction
an attraction between a polar molecule and the oppositely charged pole it temporarily induces in another molecule
hydrophobic
describes a repulsive interaction between a solute and water that decreases water solubility
pressure (P)
the ratio of a force to the surface area over which the force is applied
standard atmosphere (atm)
the average pressure at sea level on Earth
phase diagram
a graphical representation of the dependence of the stabilities of the physical states of a substance on temperature and pressure
triple point
the temperature and pressure at which all three phases of a substance coexist
critical point
a specific temperature and pressure at which the liquid and gas phases of a substance have the same density and are indistinguishable from each other
supercritical fluid
a substance in a state that is above the temperature and pressure at the critical point, at which the liquid and vapor phases are indistinguishable
green chemistry
laboratory practices that reduce or eliminate the use or generation of hazardous substances
surface tension
the ability of the surface of a liquid to resist an external force
meniscus
the concave or convex surface of a liquid