04 - Melt flow behaviour

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Last updated 12:47 PM on 6/12/26
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6 Terms

1
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Definition of melt flow behaviour

How a thermoplastic material in its molten state deforms & flows under the influence of temperature & shear stress

2
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Definition of viscosity

A measure of the fluid’s resistance to flow

→ quantifies how easily the fluid deforms under shear stress

→ high viscosity = high resistance to flow (e.g. honey)

→ low viscosity = low resistance to flow (e.g. water)

3
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Give some examples of high & low viscosity materials

Low viscosity

  • air

  • Water

  • Olive oil

High viscosity

  • honey

  • Glass

4
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What’s the particularity of plastics about viscosity?

They exhibit a wide range of viscosities

(100 → 1 000 000)

5
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What’s the shear rate?

What are the 3 different types of fluids that we get depending on the shear rate?

What is its influence on the required shear stress to induce a flow & on the viscosity for each fluid?

Draw 2 graphs to illustrate your explanations

Shear rate = how fast the layers of a liquid slide past each other

4 types of fluids

  • Bingham

→ needs a minimum shear stress to start flowing (below it, it behaves like a solid, no flow, once it’s reached, it flows like a Newtonian fluid)

→ once the stress is reached, the viscosity remains constant

→ e.g. ketchup

  • dilatant fluid

→ the required shear stress increases more rapidly than the shear rate

→ viscosity first constant & then increases for higher shear rates

→ e.g. starch corn + water

Note: the ease to penetrate the liquid depends on the speed with which the force is applied)

  • Newtonian fluid

→ shear stress & shear rate are proportional

→ viscosity remains constant

→ e.g. air

  • pseudo-plastic fluid

→ shear stress increases more slowly than the shear rate

→ viscosity first constant & then decreases for higher shear rates

→ e.g. blood

<p>Shear rate = how fast the layers of a liquid slide past each other</p><p></p><p><strong>4 types of fluids</strong></p><ul><li><p><strong>Bingham</strong></p></li></ul><p>→ needs a <strong>minimum shear stress</strong> to start flowing<em> (below it, it behaves like a solid, no flow, once it’s reached, it flows like a Newtonian fluid)</em></p><p>→ once the stress is reached, the <strong>viscosity</strong> remains <strong>constant</strong></p><p><em>→ e.g. </em><strong><em>ketchup</em></strong></p><p></p><ul><li><p><strong>dilatant fluid</strong></p></li></ul><p>→ the required shear stress <strong>increases more rapidly</strong> than the shear rate</p><p>→ viscosity <strong>first constant</strong> &amp;<strong> then increases</strong> for higher shear rates</p><p><em>→ e.g. </em><strong><em>starch corn + water</em></strong></p><p><em>Note: the ease to penetrate the liquid depends on the speed with which the force is applied)</em></p><p></p><ul><li><p><strong>Newtonian fluid</strong></p></li></ul><p>→ shear stress &amp; shear rate are <strong>proportional</strong></p><p>→ viscosity remains <strong>constant</strong></p><p><em>→ e.g. </em><strong><em>air</em></strong></p><p></p><ul><li><p><strong>pseudo-plastic fluid</strong></p></li></ul><p>→ shear stress <strong>increases more slowly </strong>than the shear rate</p><p>→ viscosity <strong>first constant </strong>&amp;<strong> then decreases</strong> for higher shear rates</p><p><em>→ e.g. </em><strong><em>blood</em></strong></p><p></p>
6
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What other factors than the shear rate can influence the melt flow behaviour of thermoplastics?

How do they affect it?

Sketch a graph to illustrate it

  • Molecular mass

Increased molecular mass → increased molecules’ length → increased viscosity

(Because the molecules are more likely to entangle)

  • filler content

Increased filler content = increased viscosity

  • plasticisers

Increased plasticisers = decreased viscosity

  • pressure

Increased pressure = increased viscosity

  • temperature

Increased temperature = decreased viscosity

<ul><li><p><strong>Molecular mass</strong></p></li></ul><p>Increased molecular mass → increased molecules’ length → increased viscosity</p><p><em>(Because the molecules are more likely to entangle)</em></p><p></p><ul><li><p><strong>filler content</strong></p></li></ul><p>Increased filler content = increased viscosity</p><p></p><ul><li><p><strong>plasticisers</strong></p></li></ul><p>Increased plasticisers = <strong><u>decreased</u></strong> viscosity</p><p></p><ul><li><p><strong>pressure</strong></p></li></ul><p>Increased pressure = increased viscosity</p><p></p><ul><li><p><strong>temperature</strong></p></li></ul><p>Increased temperature = <strong><u>decreased</u></strong> viscosity</p>