Chemistry: an atoms-focused approach - CH 4: Chemical Bonding

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22 Terms

1

chemical bond

strong attractive forces which hold atoms together

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2

ionic bonding

bonding that results in the transfer of one or more atoms to another

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3

covalent bonding

bonding that results from the sharing of one or more electron pairs by two atoms

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4

metallic bonding

bonding that results from attraction of positively charged metal ions for mobile electrons that are delocalized throughout the metallic crystal

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5

lattice enthalpy

the energy necessary to separate the ions of an ionic solid into isolated gas phase ions

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6

octet rule

States that atoms lose, gain or share electrons in order to acquire a full set of eight valence electrons

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7

Lewis Dot Structure

diagram of a molecule using dots to represent valence electrons

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8

double bond

A chemical bond formed when atoms share two pairs of electrons

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9

triple bond

A chemical bond formed when atoms share three pairs of electrons

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10

incomplete octet

These elements are stable with fewer than eight electrons in their valence shell and include hydrogen (2), helium (2), lithium (2), beryllium (4), and boron (6).

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11

expanded octet

when a molecule has more than 8 electrons around the central atom

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12

odd electron species

molecules or ions with an odd number of electrons

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13

Electron negativity

measure of the ability of an atom in a molecule to attract bonding electrons to itself

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14

dipole moment

measure of the degree of charge separation in a bond of in a molecule

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15

formal charge

the hypothetical charge that an atom in a molecule acquires when the bonding electrons are assumed to be shared equally between the atoms

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16

Resonance

the bonding in molecules or ions that cannot be correctly represented by a single Lewis structure

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17

delocalized bonding

a type of bonding in which a bonding pair of electrons is spread over a number of atoms rather than localized between two

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18

bond length

the average distance between the nuclei of two bonded atoms

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19

bond energy

the energy required to break a chemical bond and form neutral isolated atoms

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20

bond order

the number of shared electron pairs between two atoms

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21

decreases

as bond order increases, bond length ____ (inverse relationship)

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22

increases

as bond order increases, bond energy _____ (direct relationship)

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