Aromaticity & Benzene Reactions

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21 Terms

1
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aromaticity rules

  1. cyclic and conjugated, none are SP2 

  2. 4n+2 rule 

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a compound is acidic if

deprotonation makes it aromatic

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if loss of leaving group makes a compound aromatic, then the compound is more inclined to undergo

Sn1 reactions

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meta directors

deactivating

<p>deactivating</p>
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ortho/para directors

F, CL, Br, I

activating

<p>F, CL, Br, I</p><p>activating</p>
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<p>reduction of a nitro group</p>

reduction of a nitro group

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<p>side chain reaction</p>

side chain reaction

doesnt work with tertiary!

<p>doesnt work with tertiary!</p>
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<p>DIAZONIUM SALT&nbsp;</p><p></p>

DIAZONIUM SALT 

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<p>H3PO2</p>

H3PO2

benzene ring

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<p>KI</p>

KI

I

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HBF4

F

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H3O+, heat

OH

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CuCN

CN

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CuBr

Br

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CuCl

Cl