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carbonate (CO32-)
add dilute acid
effervescence, carbon dioxide produced
chloride (Cl-) [in solution]
acidify with dilute nitric acid, then add aq silver nitrate
white ppt
iodide (I-) [in solution']
acidify with dilute nitric acid, then add aq silver nitrate
yellow ppt
nitrate (NO3-) [in solution]
add aq sodium hydroxide, then aluminium foil, warm carefully
ammonia gas produced
sulfate (SO42-) [in solution]
acidify with dilute nitric acid, then add aq barium nitrate
white ppt
aluminium (Al3+)
aq NaOH:
white ppt, soluble in excess — colourless solution
aq NH3:
white ppt, insoluble in excess
ammonium (NH4+)
aq NaOH:
ammonia gas produced on warming
calcium (Ca2+)
aq NaOH:
white ppt, insoluble in excess
aq NH3:
no ppt
copper (II) (Cu2+)
aq NaOH:
light blue ppt, insoluble in excess
aq NH3:
light blue ppt, soluble in excess — dark blue solution
iron (II) (Fe2+)
aq NaOH & aq NH3:
green ppt, insoluble in excess
iron (III) (Fe3+)
aq NaOH & aq NH3
red-brown ppt, insoluble in excess
zinc (Zn2+)
aq NaOH & aq NH3:
white ppt, soluble in excess
ammonia (NH3)
turns damp red litmus paper blue
carbon dioxide (CO2)
gives a white ppt with limewater (ppt dissolves in excess CO2)
hydrogen (H2)
“pops” with a lighted splint
oxygen (O2)
relights a glowing splint
sulfer dioxide (SO2)
turns aq acidified potassium manganate (VII) (KMnO₄) from purple to colourless