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Physical Properties
the physical characteristics of the substance, tells us how the substance behaves physically, doesn’t say anything about how the substance behaves chemically
absorption, angular momentum, area, brittleness, bp, capacitance, colour, concentration, density, ductility, elasticity, electric charge, electrical conductivity, electric field, electric potential, flow rate, fluidity, frequency, hardness, heat capacity, length, location, luminescnece, malleability, magnetic field, mass, mp, momentum, permeability, plasticity, pressure, resistivity, reflectivity, solubility, specific heat, stiffness, temp, tension, thermal conductiviy, velocity, viscosity, volume
Important for IMAT
Boiling point: temperate at which a chemical boils, i.e., liquid to gas, depends on what type of chemical, depends on pressure, high pressure = high boiling point
Melting point: the temperature at which a chemical melts (solid to liquid), depends on type of chemical, depends on pressure, generally, higher pressure = higher melting point, Exception: ice to water
Freezing point: the temperature at which a chemical freezes (liquid to solid) depends on type of chemical, depends on pressure, generally higher pressure = higher freezing point
Exceptions (there are many): water to ice
For melting point and freezing point there are quite a few exceptions, so it’s not really a general rule of how pressure impacts the freezing or melting point.
Chemical Properties
the chemical characteristics of the substance
Heat of combustion
Explosivity
Enthalpy of formation
Toxicity
Chemical stability
Flammability
Preferred oxidation state
Ability to corrode
Combustibility
Acidity/Basicity
Phase Change: the transition from one physical state of matter to another
Is a physical process, influenced by both temperature and pressure
Boiling point
Melting point
Triple point: unique temperature and pressure at which solid, liquid and gas all coexist in equilibrium
Critical point: temperature and pressure at which liquid and gas phases become indistinguishable. Liquid and gas basically become the same phase (supercritical fluid)
Phase Changes
From Solid….
To liquid: melting
To gas: sublimation
From liquid…
To solid: freezing
To gas: vaporisation
From gas…
To solid: deposition
To liquid: condensation
To plasma: ionisation
From plasma to gas: recombination
Properties of water
Cohesion: how molecules stick together, e.g. via H-bonds, the stronger the cohesive bonds, the more the liquid will try to minimize surface area, sphere = minimize surface area
Water is polar, the molecules are attracted to each other,
Adhesion: water attracts other substances, overcome the adhesive forces, e.g. water and glass
Concave meniscus: water attracted to glass, polar + polar
Convex meniscus: mercury + glass, non-polar, minimize surface area
Surface Tension
Energy required to increase the surface area of a liquid
Depends on cohesive forces, water has high surface tension due to H bonds
Hydrogen bonds: weak bonds form and break continuously, strongest intermolecular force.
Capillary action
Process of a liquid flowing in a material because of cohesive and adhesive forces
Allows water and nutrients to be transported in plants
Due to both adhesive and cohesive forces
Viscosity
Resistance to flow
Water have low viscosity compared to honey
Increases viscosity:
Stronger intermolecular forces
Larger molecules
Lower temperatures