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what are the three forms of iron alloys
wrought iron, steel, cast/pig iron
properties of iron and steel
hard, opaque, malleable, metallic, conductive, magnetic, strong
how much carbon is in wrought iron
0-0.2%
how much carbon is in steel
0.2-2.1%
how much carbon is in cast iron/pig iron?
2.3-4.3%
properties of wrought iron
pure, ductile, high melting point
properties of steel
very strong, hard, forgable, 1000x harder than pure iron, high melting point
properties of cast iron/pig iron
low melting point, brittle, not forgable (must be cast)
how does the melting point change as the concentration of carbon increases?
it decreases
annealing
heat it and slow cool it (get rid of dislocations) (makes it bendier)
quenching
heat it and rapid cool it (locks it up because the carbon couldn’t get where it wanted to go)
tempering
quench then heat again
puddling
converting pig iron into wrought iron or steel by heating it and frequently stirring it in a furnace with oxidizing substances
bloomery furnace
makes wrought iron; ore and charcoal are repeatedly heated in a furnace and beaten until left with only iron
blast furnace
makes cast iron; heat ore, charcoal, and limestone unitl the liquid iron can be collected from the bottom
finery forge
converts cast iron to wrought iron; re-melt cast iron until the carbon and silicon oxidize out to produce bloom and slag, then beat into wrought iron
carborization
converts wrought iron to steel; heat iron in carbon rich air
bessimer furnace
converts cast iron to steel using BOP
BOP
basic oxygen process; inject pure oxygen and add alloying agents and carbon after oxidizing impurities
coking
driving sulfer out of coal
creative destruction
eliminating old ways fo doing things and introducing new ways of doing things
Carnegie’s Roots
born in scotland, dad was a hand loom weaver of linen until he was put out of work by a factory of machines, moves to US in 1845, became a telegraph operator for the pennsylvania railroad (speeds up to 35-40 mph)
hard driving
working equipment until it breaks down and then replacing it
vertical integration
purchased sources of raw materials
aluminum properties
durable, lightweight, ductile, nonmagnetic, difficult to weld
phlogiston
Becher thought burning something gave off phlogiston and left calx
Antoine Lavoisier
proves that oxygen was necessary for combustion (theory proposed by Joseph Priestley)(first to organize elements by weight)
Joseph Priestly
isolated oxygen from mercury oxide using sunlight
oxide reduction
a reactant gains or loses electrons
Hall-heroult Process
dissolve aluminum oxide into cryolite because of its lower melting point, then use Bayer process to convert the resulting bauxite back to aluminum oxide
history of aluminum
price dropped dramtically
solid solution hardening
alloying
work hardening
create dislocations by bending
precipitation hardening
add copper or sillcon to aluminum and heat to a low temperature to precipitate dislocations
cyclic fatigue
repeated tensile-compressive stress
economic deflation
so much aluminum was produced that the price dropped
amorphous metal
metal with crystalline glass structure
history of writing
tablets, walls, parchment, paper
papyrus
3000 BC - earliest for of paper making
parchment
thinned and stretched animal skin
linseed oil
stains wood
mechanical pulping
wood chips soaked in hot water then ground - lignin remains, higher yeild, cheaper, less pollution
chemical pulping
sodium hydroxide and sodium sulfide separate cellulose and lignin, the lignin is dissolved in liquor and washed away
cellulose
44% of dry wood, organic polymer
lignin
27% of dry wood, binds cellulose together
four functions of money
unit of account, store of value, medium of exchange, standard of deffered payment
polymers
a long chain molecule made of repeat units called “mers”
cellulose nitrate
wood + nitric and sulfuric acid - transparent
polyethylene
hydrogen side groups; most common plastic
polypropylene
CH3 side groups; thermoplastic
polyvinylchloride
Cl side groups
polystyrene
Benzene side groups- styrofoam
rubber
natural polymer
vulcanization
rubber is heated with sulfer to form corss links between the molecules
condensation polymerization
water is produced by the reaction
3 marketing strategies
sell the need, make it seem unique, dominant image with scientific fact
silicon properties
high melting point, reflective, shiny, brittle
dopants
adding Si or Ge making it conductive
p-type
adding a group III element (boron) makes holes
n-type
adding a group V element (arsenic or phosphorus)
transistor
can serve as an amplifier or switch, n-type silicon is deposited with gaps onto a layer of p-type silicon
moore’s law
the number of transistors in a circuit will double every 2 years
integrated circuit
multiple functions can now be put on a singular chip