CHM-232 Quiz 1 - Alkynes

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15 Terms

1
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NaNH2

double dehydrohalogenation, terminal alkyne

2
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KOH

double dehydrohalogenation, internal alkyne

3
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NaNH3

alkyne -> trans alkene

4
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Lindlar’s catalyst

alkyne -> cis alkene

5
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HgSO4/H2SO4

triple -> double, Mark add H and OH, ketone

6
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1 eq. X

cis/trans alkenes

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2 eq. X

tetrahalides

8
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Hg2+ catalyzed hydration

Mark add H2O -> enol -> ketone

9
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Sia2BH

hydroboration

10
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H2O2/NaOH

anti-Mark hydration -> enol -> ketone

11
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KMnO4/O3

oxidative cleavage

12
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H2/Pd, Pt, Ni

alkane

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enol

OH-C=C

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aldehyde

RH>C=O

15
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ketone

RR>C=O