Adv. Chem. Midterm

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64 Terms

1

moles

unit of measurement represented by "n"

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2

molar mass

the mass of one mole of a pure substance

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3

periodic table

an arrangement of elements in which the elements are separated into groups based on a set of repeating properties

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4

avogadro's number

number of representative particles in a mole, 6.02 X 10^23

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5

atoms

smallest unit of matter

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6

isotopes

Atoms of the same element that have different numbers of neutrons

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7

average atomic mass

weighted average of the atomic masses for the isotopes of an element

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8

solid

Definite shape and volume

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9

liquid

the state of matter that has a definite volume but not a definite shape

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10

gas

A state of matter with no definite shape or volume

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11

formula units

the lowest whole-number ratio of ions in an ionic compound

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12

empirical formula

a chemical formula showing the ratio of elements in a compound rather than the total number of atoms

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13

homogeneous mixture

A mixture in which substances are evenly distributed throughout the mixture

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14

heterogeneous mixture

A mixture in which different materials can be distinguished easily

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15

chromatography

A laboratory technique used to separate mixtures of molecules

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16

electron configurations

the arrangement of electrons in an atom

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17

dalton's theory

all matter is made up of individual particles called atoms, which cannot be divided

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18

coulomb's law

The relationship among electrical force, charges, and distance: The electrical force between two charges varies directly as the product of the charges and inversely as the square of the distance between them.

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19

the bohr model

model of the atom in which electrons move rapidly around the nucleus in paths called orbits

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20

the aufbau principle

An electron occupies the lowest-energy orbital that can receive it

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21

the pauli exclusion principle

states that a maximum of two electrons can occupy a single atomic orbital but only if the electrons have opposite spins

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22

hund's rule

states that single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins can occupy the same orbitals

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23

noble gas shortcut

A shorthand way to write electron configurations. Write the noble gas followed by the rest of the electron configuration that follows the noble gas.

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24

valence electrons

Electrons on the outermost energy level of an atom

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25

core electrons

inner electrons

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26

ionization energy

the energy required to remove an electron from an atom

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27

atomic radius

size of an atom

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28

nuclear charge

the total charge of all the protons in the nucleus

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29

electron

A subatomic particle that has a negative charge

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30

electron repulsion

A repulsive force caused by the similar negative charge of two or more electrons.

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31

ionic radius

Distance from the center of an ion's nucleus to its outermost electron

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32

electronegativity

the ability of an atom to attract electrons when the atom is in a compound

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33

metal

an element that is shiny and that conducts heat and electricity well

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34

nonmetal

an element that conducts heat and electricity poorly

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35

polar covalent bonds

unequal sharing of electrons

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36

nonpolar covalent bonds

equal sharing of electrons

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37

cation

A positively charged ion, smaller than neutral

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38

anion

A negatively charged ion, larger than neutral

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39

dimensional analysis

A way to analyze and solve problems using the units, or dimensions, of the measurements

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40

lewis dot structure

diagram of a molecule using dots to represent valence electrons

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41

VSEPR

Valance Electron Pair Repulsion model / Unshared electron pairs around the central atom

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42

Covalent

A chemical bond that involves sharing a pair of electrons between atoms in a molecule

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43

Ionic

transfer of electrons

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44

metallic bond

a bond formed by the attraction between positively charged metal ions and the electrons around them

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45

resonance

the bonding in molecules or ions that cannot be correctly represented by a single Lewis structure

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46

polarity

Molecules having uneven distribution of charges

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47

dipoles

positive and negative charged ends of a polar covalent molecule

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48

Planck's Constant

6.626 x 10^-34

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49

Wavelength

The distance between two corresponding parts of a wave

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50

Frequency

the number of complete wavelengths that pass a point in a given time

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51

extensive property

a property that depends on the amount of matter in a sample

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52

intensive property

a property that depends on the type of matter in a sample

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53

half life

length of time required for half of the radioactive atoms in a sample to decay

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54

molecular formula

A chemical formula that shows the number and kinds of atoms in a molecule, but not the arrangement of the atoms. The real number of atoms/elements needed to form compound.

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55

mole highway

Grams --> Mole : Mass/Molar Mass \n Mole --> Atom : Mole # x 6.02E23 \n Atom --> Mole : Mole #/6.02E23 \n Mole --> Grams : Mass x Molar Mass

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56

heating curve

a diagram that shows the temperature changes and changes of state of a substance as it is heated; Solid melts to liquid, liquid evaporates to gas. Gas condenses to liquid, liquid freezes to solid

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57

Significant Figure Rules

  1. non-zeros are always significant;

  2. zeros between two other sig figs are significant;

  3. all final zeros after the decimal point are significant;

  4. zeros used solely for spacing the decimal point are not significant unless a decimal point is present

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58

alkali metals

Group 1, 1 electron in outer level, very reactive, soft, silver, shiny, low density; Lithium, Sodium, Potassium, Rubidium, Cesium, Francium

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59

alkaline metals

metallic elements in group 2 of the periodic table which are harder than the alkali metals and are also less reactive

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60

halogens

Contains nonmetals, 7 valence electrons in it's outermost energy level. Very reactive

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61

noble gases

Elements in group 8A of the periodic table. Have no charge and are gases under normal conditions. (Helium, Neon, Argon, Krypton, Xenon, Radon)

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62

octet rule

States that atoms lose, gain or share electrons in order to acquire a full set of eight valence electrons

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63

octet rule exceptions

-Hydrogen (has only 2) \n -Lithium, Beryllium, and boron (less than 8) \n -all period 3 and below can hold >8

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64

molecular shapes

Linear, Bent (lone pairs) , Trigonal Planar, and Trigonal Pyramidal (lone pair)

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