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What properties can help predict the solubility of a substance
Atomic size and ionic charge
What happens to solubility as you move down a group on the periodic table?
Solubility decreases due to increasing atomic size, which reduces the solvation by water molecules
Solubility increases for what substances?
Salts and compounds containing alkali metals and nitrate ions
What happens to solubility when moving across a period?
The solubility predictions are more complex as it is based on the ions and anions involved
What compounds are generally soluable?
Most chlorides, bromides, and iodides are soluble
What compounds are the excecptions?
Lead, mercury, and silver
Why are lead, mercury, and silver generally insoluble
The attraction between these metals is too strong to break apart, which makes the bonds difficult to break apart
What is the process of water molecules surrounding and interacting with dissolved ions
Solvation
How does the ionic size affect solubility
As you move down a group the ionic size increases which makes it harder for water molecules to surround and solvate them
What happens to metal cation solubility as you move a group?
It decreases
Why does metal cation decrease as you move down a group?
The ionic radius of metal cations increases, which weaken hydration interactions with water molecules
How are solubility trends across a period?
They’re more complex and variable
What are solubility charts used for?
Tools for predicting whether double replacement reactions will occur
What happens if products are insoluble
They form precipitates
What happens if all products are soluable
No reaction takes place
Why do ionic compounds dissolve in water?
Water is a polar molecule so it has a partial negative charge on the oxygen atom, and a partial positive charges on the hydrogen atom. These charges attract the ions in salt which allows dissolution to occur
What is an unsaturated solution?
A solution that can still dissolve more solute
What is a saturated solution?
A solution that has dissolved the maximum amount of solute possible at that temperature. Any additional solute will remain solid
What is a dilute solution?
A solution with a low concentration of solute
What is a concentrated solution?
A solution with a high concentration of solution
What is a supersaturated solution?
A solution that contains more solute than it can normally hold at that temperature (unstable)
What is Calcium Carbonate found in
Found in antacid used for stomach aches which may produce unwanted gams
How does temperature affect solubility
Increasing temp increases solubility for most solids, while decreasing solubility of gases
How does pressure affect solubility
Increasing the pressure of a gas above a liquid increases the amount of gas that can be dissolved in the liquid (Doesn’t really affect solids)
How does molecular size affect solubility?
Larger molecules are less soluble
How does Surface Area affect solubility
It does not affect solubility, but it affects the rate of dissolving
How does the size of surface area affect the rate
A larger surface area exposes more solute particles to the solvent, leading to more frequent collisions and a faster rate of dissolution
What dissolves faster, powdered or granulated sugar?
Powdered dissolves faster because it has a much larger surface area
How does type of solvent/solute particles affect solubility
“Like dissolves Like”
What factor does not affect the rate of dissolving
Solubility
What affects the total amount of sugar that can be dissolved?
The solvent and temp
Why does increasing temp increase solubility
The higher temp means the particles are moving faster, so there is more contact, making it easier for the sugar to dissolve
What is Concentration?
A broader term for the amount of substance (solute) in a given amount of another substance (solvent)
What is Molarity
The number of moles of solute per liter solution (mol/L)
What does 1.25 M of solution mean?
There are 1.25 Moles of solute per 1 L of solution
What is Mass Concentration
Mass of solute divided by volume of solution
What is weight percent
Mass of solute divided by the total mass of the solution multiplied by 100