Alcohol and Phenols Reactions

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Last updated 2:55 AM on 9/16/26
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14 Terms

1
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Ketone/ Aldehyde to Alcohol (Reduction)

  • NaBH4, MeOH

  • 1) LiAlH4. 2) H3O+


2
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Carboxylic Acid to Alcohol (Reduction)

1) xs LiAlH4

2) H3O+

3
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Ester to Alcohol (Reduction)

1) xs LiAlH4

2) H3O+

4
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Alcohols Grignard Reagents

Ketone —> Alcohol & add Carbons

1) RMgBr

2) H3O+

5
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Alcohols Grignard Reagents

Ester —> Alcohol & add 2x Carbons

1) xs RMgBr

2) H3O+

6
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Protecting Reagents

TMSCl

Et3N

7
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Deprotecting Reagents

TBAF

or H3O+

8
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Substitutions

HI

HBr

HCl / ZnCl2

9
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SN2 Rxns —> Br & Cl

  • 1) TsCl, Py 2) NaBr

  • PBr3


  • SOCl2, Py


10
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Eliminations

  • Conc. H2SO4 , heat

  • 1) TsCl, Py. 2) t-BuOK


11
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Oxidation

Secondary Alcohol

Make Ketone

Na2Cr2O7

H2SO4, H2O

12
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Oxidation

Primary Alcohol

Make Carboxylic Acid

Na2Cr2O7

H2SO4, H2O

13
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Oxidation

Primary Alcohol

Make Aldehyde

PCC or

DMP or

1) DMSO, (COCl)2. 2) Et3N

14
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Oxidation

Phenol

Make Benzoquinone

Na2Cr2O7

H2SO4, H2O