Organic Chemistry Aromaticity & Benzene Reactions (DAT)

Benzene + Na, NH3, EtOH —>

Na, NH3, and EtOH are all reagents involved in the ___ reduction

birch

What is the product of the following reaction

What is the product of the following reaction

Nitrobenzene + H2, Pd/C —>

aniline

Nitrobenzene + Sn, HCl —>

aniline

Nitrobenzene + Zn(Hg), HCl, heat —>

aniline

Benzene + Cl₂ —>

chlorobenzene

Benzene + AlCl₃ —>

chlorobenzene

Benzene + FeBr₃ —>

bromobenzene

Benzene + SO₃, H₂SO₄ —>

benzenesulfonic acid

Benzene + HNO₃, H₂SO₄ —>

nitrobenzene

Benzene + R-Cl, AlCl₃ —>

benzene-R

Benzene + R-COCl, AlCl₃ —>

Benzene-C(=O)R

Benzene + CO, HCl, AlCl₃ —>

benzaldehyde

Friedel-Crafts actylation and alkylation do not work with

NO2 and NH2

What is the product in this reaction

The following reaction results in the ___ (p/m) product

para

The following reaction results in the ___ (p/m) product

meta

The following are examples of ___ groups: CN, NR3, NO2, COR, COOH, COOR, SO3H

ewg

The following are examples of ___ groups: Sr, SH, R, OH, OR, ether, amide

edg

F, Cl, Br, and I are ___ directors

ortho para

Electron withdrawing groups are ___ directors

meta

Electron donating groups are ___ directors

ortho para

Benzene-CH-R2 + KMnO4 —>

benzoic acid

In order for benzylic oxidation to occur, the benzylic carbon must be bound to at least one

hydrogen

Analine + NaNO₂, HCl —>

benzene-N2, diazonium salt

Diazonium salt + H₃PO₂ —>

benzene

Diazonium salt + KI —>

iodobenzene

Diazonium salt + HBF₄ —>

fluorobenzene

Diazonium salt + H₃O+, heat —>

phenol

Diazonium salt + CuCN —>

cyanobenzene

Diazonium salt + CuBr —>

bromobenzene

Diazonium salt + CuCl —>

chlorobenzene