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dissociation
breaking apart into ions
Arrhenius acid
a substance that produces H+ when dissolved in water
this means according to this definition, all acids must have at least 1 hydrogen
H+ is synonymous with the hydronium ion: H3O+
Properties of acids:
acids have a sour taste and would burn if put onto skin
when a strong acid is added to a strong base, they form water. This is called a neutralization reaction
acids corrode metal, which means that when they react, hydrogen gas is formed
strong acids
HCI, HBr, HI, HNO3, H2SO4, HCIO4
Properties of Bases:
Arrhenius base: a substance that produces OH- when dissolved
Bases taste bitter and feel slippery to the touch
when a base comes into contact with proteins, it denatures them
Strong bases
group 1 or group 2
pH
a measure of how acidic or basic a substance is
pH of an acid: <7
pH of a base: >7
no units for pH
pH and pOH
pH= -log[H+]
pOH= -log[OH-]
relationship between pH and pOH:
pH + pOH= 14.00
Find pH
[H+] = 0.00576 M
Find pOH:
[OH-] = 0.0554 M
Undoing pH
[H+] = 10^-pH
Undoing pOH:
[OH-] = 10^-pOH
What is the molarity of H+ if the pH is 6.70?
What is the molarity of H+ if pOH is 3.57?
naming acids
binary acids: H and 1 other element on periodic table
prefix: hydro-
suffix: -ic
ex: HCl —> hydrochloric acid
polyatomic acids
H + polyatomic anion
based off polyatomic ion name + ic
ex: HC2H3O2 - acetic acid
oxyanions- keep prefix, change ending
ate 🡪 -ic
ite 🡪 -ous
ex: H2CO2 - carbonous acid
Ex. What is the pH and pOH of a 2.34 x 10-5M HClO4 solution?
pH = -log (2.34 x 10-5 ) = 4.63
pH + pOH = 14.00
4.63 + pOH = 14.00
pOH = 9.37
Ex. What is the pH and pOH of a 7.9 x 10-12M NaOH solution?
pOH = - log (7.90 x 10-12 )
= 11.1
pH + pOH = 14.00
pH = 14.00 - 11.1
= 2.9
Ex. The pOH of a solution is 10.25, what is the [H+]? The [OH-]?
pH = 14.00- 10.25
= 3.75
[OH-] = 10 ^ -10.25
= 5.62 x 10-11M
[H+] = 10 ^ -3.75
= 1.78 x 10 -4 M
Ex. What is the [H+] if the pH is 9.50? What is the [OH-]?
pOH = 14.00 - 9.50
= 4.50
[H+] = 10 ^ -9.50
= 3.16 x 10 -10 M
[OH-] = 10 ^ -4.50
= 3.16 x 10-5 M
Titrations
Method of finding the unknown molarity of a solution by reacting it with a solution of known concentration.
Tips
Never fill when buret is above your eye level. This is dangerous.
The final solution should be the lightest pink possible. Use white paper underneath to help.
you can use a first trial to go fast (approx result). then slow down your subsequent trials for more accurate results
What is the pH and pOH of a 2.34 x 10-5M
HClO4 solution?
pH = 4.631, pOH = 9.369
What is the [H+] if the pH is 9.50? What is the
[OH-]?
[H+] = 3.2 x 10-10 M
pOH = 4.50, [OH-] = 3.2 x 10-5 M
Bronsted-Lowery’s definitions
acid-substance that donates an H+
base-substance that accepts an H+
Conjugate acid
the acidic form of the original base (formed when the base accepts the H+)
conjugate base
the basic form of the original acid(formed when the acid donates the H)
Label the acid, base, conjugate acid, conjugate
base: NH3 + HClO 🡨🡪 NH4+ + ClO-
base
acid
conj acid
conj base
amphoteric
a substance that can act as an acid or base
can accept an H+ or give an H+
ex: H2O
titrations
used to determine a unknown concentration
titrant
solution of known concentration
analyte
solution of unknow concentration
indicator
changes color:
when pH changes
at the equivalence point
equipment
~Buret
-contains titrant
~Erlenmeyer flask
-contains analyte and indicator
~ring stand
~buret clamp
-attaches buret to ring stand