Chemical Kinetics

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8 Terms

1
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First Order Integrated Rate Law

[A] = [A]0e-kt

2
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Second Order Integrated Rate Law

1/[A] = kt + 1/[A]0

3
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How do you solve for K for first order kinetics with a dataset?

Make another column for ln[A], then calculate the slope

4
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How do you solve for K for second order kinetics with a dataset?

Make a column of 1/[A] and find the slope

5
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Half-Life for First Order Kinetics

t1/2 = ln(2)/K

6
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Half-Life for Second Order Kinetics

t1/2 = 1/K[A]0

7
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Rf/Rr =

K/Q

8
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slope =

-Ea/R