Chapter 4 – Stoichiometry of Chemical Reactions (Sections 4.1 & 4.2)

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Vocabulary flashcards summarizing essential terms from the lecture on writing, balancing, and classifying chemical reactions.

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22 Terms

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Chemical Equation

A symbolic representation of a chemical reaction showing formulas of reactants and products, their physical states, and relative quantities.

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Balanced Chemical Equation

An equation in which equal numbers of each type of atom appear on both the reactant and product sides.

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Reactants

Substances that undergo change in a chemical reaction; written to the left of the arrow in an equation.

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Products

Substances produced by a chemical reaction; written to the right of the arrow in an equation.

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Coefficient

Whole number placed in front of a chemical formula to indicate the relative number of molecules or moles; omitted when the value is 1.

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Balancing by Inspection

Method of balancing an equation by adjusting coefficients until atom counts are equal on both sides.

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Mole Ratio

The proportional relationship between coefficients in a balanced equation, expressing relative amounts of reactants and products.

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(g), (l), (s), (aq)

Parenthetical symbols indicating a substance’s physical state: gas, liquid, solid, or aqueous (dissolved in water).

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Δ (delta) over the arrow

Notation used to show that heat is supplied to drive a reaction.

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Molecular Equation

Chemical equation that shows compounds as complete, neutral formulas without detailing their ionic character in solution.

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Complete Ionic Equation

Equation in which all strong electrolytes are written as separate ions to show the actual species present in aqueous solution.

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Spectator Ion

Ion that appears unchanged on both sides of a complete ionic equation and does not participate in the net reaction.

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Net Ionic Equation

Equation that shows only the chemical species that actually change during the reaction, excluding spectator ions.

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Precipitation Reaction

Reaction in which dissolved substances form one or more solid products (precipitates); also called double displacement or metathesis reaction.

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Solubility

Maximum concentration of a substance that can dissolve in a solvent at specified conditions; high solubility ⇒ soluble, low solubility ⇒ insoluble.

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Solubility Rules

Empirical guidelines predicting whether common ionic compounds are soluble or insoluble in water.

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Insoluble Compound

Substance with very low solubility that readily precipitates from solution when its concentration exceeds its solubility limit.

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Double Displacement (Metathesis) Reaction

Reaction type where two ionic compounds exchange ions to form two new compounds, often producing a precipitate or water.

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Stoichiometry

Area of chemistry that deals with the quantitative relationships between reactants and products in a chemical reaction.

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Aqueous Solution

Homogeneous mixture in which a substance (solute) is dissolved in water (solvent), designated with (aq).

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Fractional Coefficient (Intermediate)

Non-integer coefficient temporarily used while balancing an equation, later cleared by multiplying all coefficients by a whole number.

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Spectator-free Reaction Example

Ag⁺(aq) + Cl⁻(aq) → AgCl(s); illustrates a net ionic equation after spectator ions are removed.