Isomers

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Last updated 12:53 AM on 8/5/26
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27 Terms

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Lewis structures

Diagrams that represent the bonding between atoms of a molecule and the lone pairs of electrons.

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VSEPR theory

Valence Shell Electron Pair Repulsion theory; explains the three-dimensional shape of molecules based on electron pair arrangements.

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Hybridisation

A quantum mechanical model describing how atomic orbitals mix to form new hybrid orbitals for bonding.

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Carbon scaffold

The arrangement of carbon atoms in organic compounds, influencing the position of reactive heteroatoms.

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Tetrahedral Geometry

A molecular shape with four bonds arranged around a central atom at approximately 109.5° angles, associated with sp3sp^3 hybridisation.

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Trigonal Planar Geometry

A molecular shape with three bonds arranged around a central atom at 120° angles, associated with sp2sp^2 hybridisation.

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Linear Geometry

A molecular shape with two bonds arranged around a central atom at 180° angles, associated with spsp hybridisation.

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Line Structure

A representation of organic molecules that uses lines to denote bonds, simplifying complex structures.

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Condensed Formula

A representation that indicates connectivity in a molecular structure, often bypassing detailed bonding information.

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Structural Formula

A detailed two-dimensional representation that shows every atom and bond in a molecule.

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Traditional 3-D Representation

Uses wedges and dashes to indicate three-dimensional relationships between atoms in a molecule.

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Ball-and-Stick Models

3D models that illustrate the shape and size of molecules, with color-coded atoms.

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Space-Filling Models

3D representations that show the volume occupied by electron clouds, obscuring individual bonds.

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Isomers

Compounds with the same molecular formula but different structures or spatial arrangements.

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Constitutional Isomers

Isomers that differ in the arrangement of bonds among their atoms.

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Stereoisomers

Isomers that have the same connectivity but differ in the three-dimensional arrangement of their atoms.

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Enantiomers

Stereoisomers that are non-superposable mirror images of each other.

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Diastereoisomers

Stereoisomers that are not mirror images and differ in physical properties.

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Chirality

A property of asymmetry where a molecule is not superimposable on its mirror image.

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Optical Activity

The ability of chiral molecules to rotate plane-polarized light.

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Fischer Projections

A two-dimensional representation of a three-dimensional organic molecule that preserves stereochemical information.

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Meso Compound

A compound with multiple stereogenic centers that is superimposable on its mirror image due to internal symmetry.

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E/Z System

A naming system for stereoisomers that designates configurations based on the relative positions of substituents around double bonds.

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Combustion Reaction

A chemical reaction in which a substance combines with oxygen, producing heat and light, typically carbon dioxide and water as byproducts.

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Hybridisation in Functional Groups

The concept pertaining to the types of hybridised orbitals involved in various functional groups in organic compounds.

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Chemical Properties of Hydrocarbons

Attributes of hydrocarbons, often characterized by their stability, reactions, and combustion.

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Lock and Key Concept

A hypothesis describing the specific interaction between a molecule (the key) and a receptor (the lock), crucial in biochemistry.