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Lewis structures
Diagrams that represent the bonding between atoms of a molecule and the lone pairs of electrons.
VSEPR theory
Valence Shell Electron Pair Repulsion theory; explains the three-dimensional shape of molecules based on electron pair arrangements.
Hybridisation
A quantum mechanical model describing how atomic orbitals mix to form new hybrid orbitals for bonding.
Carbon scaffold
The arrangement of carbon atoms in organic compounds, influencing the position of reactive heteroatoms.
Tetrahedral Geometry
A molecular shape with four bonds arranged around a central atom at approximately 109.5° angles, associated with sp3 hybridisation.
Trigonal Planar Geometry
A molecular shape with three bonds arranged around a central atom at 120° angles, associated with sp2 hybridisation.
Linear Geometry
A molecular shape with two bonds arranged around a central atom at 180° angles, associated with sp hybridisation.
Line Structure
A representation of organic molecules that uses lines to denote bonds, simplifying complex structures.
Condensed Formula
A representation that indicates connectivity in a molecular structure, often bypassing detailed bonding information.
Structural Formula
A detailed two-dimensional representation that shows every atom and bond in a molecule.
Traditional 3-D Representation
Uses wedges and dashes to indicate three-dimensional relationships between atoms in a molecule.
Ball-and-Stick Models
3D models that illustrate the shape and size of molecules, with color-coded atoms.
Space-Filling Models
3D representations that show the volume occupied by electron clouds, obscuring individual bonds.
Isomers
Compounds with the same molecular formula but different structures or spatial arrangements.
Constitutional Isomers
Isomers that differ in the arrangement of bonds among their atoms.
Stereoisomers
Isomers that have the same connectivity but differ in the three-dimensional arrangement of their atoms.
Enantiomers
Stereoisomers that are non-superposable mirror images of each other.
Diastereoisomers
Stereoisomers that are not mirror images and differ in physical properties.
Chirality
A property of asymmetry where a molecule is not superimposable on its mirror image.
Optical Activity
The ability of chiral molecules to rotate plane-polarized light.
Fischer Projections
A two-dimensional representation of a three-dimensional organic molecule that preserves stereochemical information.
Meso Compound
A compound with multiple stereogenic centers that is superimposable on its mirror image due to internal symmetry.
E/Z System
A naming system for stereoisomers that designates configurations based on the relative positions of substituents around double bonds.
Combustion Reaction
A chemical reaction in which a substance combines with oxygen, producing heat and light, typically carbon dioxide and water as byproducts.
Hybridisation in Functional Groups
The concept pertaining to the types of hybridised orbitals involved in various functional groups in organic compounds.
Chemical Properties of Hydrocarbons
Attributes of hydrocarbons, often characterized by their stability, reactions, and combustion.
Lock and Key Concept
A hypothesis describing the specific interaction between a molecule (the key) and a receptor (the lock), crucial in biochemistry.