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Which reagent can be used to distinguish phenol from benzyl alcohol?
FeCl3
Salicylic acid is stronger than benzoic acid because:
an intramolecular hydrogen bond is formed between the two functional groups
Phenols are more acidic than alcohols because:
the phenoxide ion is stabilised by resonance
The strongest acid among the following aromatic compounds is:
ortho-nitrophenol
What is the common name for CH2=CHCH2Cl:
allyl chloride
Which reagent cannot be used for preparing alkyl chlorides from alcohols?
NaCl
The reactivity of alkyl halides decreases in the following order:
RI>RBr>RCl>RF
Which compound is a homologue of ethanal?
methanal
Which compound contains an asymmetric (chiral) carbon atom
2-bromobutane
The hydrolysis of 4-chlorobenzyl chloride with a concentrated solution of sodium hydroxide results in:
p-hydroxybenzyl alcohol
The polyvalent alcohols are identified with:
freshly precipitated copper (II) hydroxide
The reactions by which m-nitrophenol can be produced from benzene are:
sulfonation, nitration, reaction with sodium hydroxide, alkali melting
The mild oxidation of which alcohol does not give a carbonyl compound?
2,3-dimethyl-3-pentanol
Which pair are metamers?
CH3OCH2CH2CH3 and CH3CH2OCH2CH3
How a solution containing benzene, naphthalene, phenol and aniline can be separated:
the phenol is extracted after treatment with sodium hydroxide, the aniline is extracted after treatment with hydrochloric acid, and benzene and naphthalene are extracted through distillation
Which halogen notably does not react with methane by the chain-linking mechanism?
iodine
Hexane may be obtained in highest yield by Wurtz method from:
1-chloropropane
The amino acids do not interact with
salts
Which of the following compounds is a product of the interaction between glucose and Fehling’s reagent:
CH2OH(CHOH)4COOH
Which of the following compounds contains an aldehyde group:
all listed compounds
How many carbon atoms in the molecule of acrylonitrile are in the sp-hybrid state
one
The maltose is:
a dissacharide consisting of glucose residues, an intermediate in the hydrolysis of starch
Which of the listed compounds interacts with bromine water?
ethyn
Characteristic reactions for alkenes are:
addition
As a result in the reaction of polycondensation is formed:
phenol formaldehyde resin
Upon interaction of phenol with bromine is formed a mixture of:
2- and 4- bromophenols
By the help of which reagent may 1-propanol and 1,2,3-propantriol be distinguished?
copper (II) hydroxide
Which of the following amino acids is achiral?
glycine
By which of the presented processes and interactions can formic acid be distinguished from ethanoic acid?
cuprum dihydroxide
With which of the compounds: ethanol, sodium hydroxide and acetic anhydride, interacts with salicylic acid?
sodium hydroxide, ethanol and acetic anhydride
Which of the folllowing will give 1-butene as the only alkene by heating with concentrated sulfuric acid?
1-butanol
Glucose and fructose may be distinguished by interaction with:
bromine water
Which is not a physical property of alcohols or phenols?
the hydroxyl group of an alcohol is nonpolar
The benzene ring of benzaldehyde substitutes at m-position to the aldehyde group, because it has:
-M and -I effect
Carbonyl derivatives do not add one of the following substances:
bromine
The molecular formula of glycerol is:
C3H5(OH)3
The interaction between which substances is an addition reaction?
ethanal and hydrogen
The colourless crystalline substance A is slightly soluble in water, it sublimes when heated, and 2 mol of NaOH are needed for the neutralisation of 1 mol of A
Substance A is:
salicylic acid
Which of the reagents can be used to identify glycerol
with an aqueous solution of FeCl3 - violet colouring
Sucrose is a carbohydrate. The molecular formula of the compound is:
C12H22O11
The use of fats with alkaline base in an aqueous medium during heating is used in the production of:
soaps
Oxidation of butanone produces:
acetic and propionic acids, CO2 and H2O
In which order are carboxylic acids arranged by increasing their acidic properties?
propionic, acetic, benzoic, formic
The vigorous oxidation of which isomer of hexene does not result in a mixture of acids?
3-hexene
In which order are the compounds arranged in order of increasing reactivity?
CH3COC2H5, CH3COCH3, CH3CHO, HCHO
Under what conditions can hydrogen atoms in the side chain of toluene be replaced by atoms of halogen elements?
under illumination at high temperature
A natural polymer is:
the rubber
Hydrogen bonds can not form between molecules of:
CH3CHO and CH3COCH3
Oxidation of ethylene (CH2=CH2) produces:
1,2-ethanediol
A phenolic hydroxyl group can be identified with a dilute aqueous solution of:
FeCl3
The equation: C2H5OH + HCOOH →←HCOOC2H5 + H2O expresses the process:
esterification
In the molecules of alpha-amino acids the groups -NH2 and -COOH are connected to:
the first carbon atom
Which of the following compounds does not react with an ammonia solution of Ag2O?
3-hexanone
The two functional groups in alpha-amino acids interact with each other and form intramolecular salts. It is due to…
the high solubility in water, the high melting point and the low solubility in organic solvents
In which hydrocarbon conversion process do the final products contain a greater number of carbon atoms than the starting substances?
Wurtz synthesis
Polymethyl methacrylate is obtained by polymerisation of:
CH2=C(CH3)COOCH3
Benzaldehyde is involved in substitution reactions affecting the aromatic nucleus. In which place are the substitutes oriented:
m-position
Which of the following acids has optical isomers?
lactic acid
Positional isomerism is possible with:
amino acids, ketones, alkynes
Which of the following substances does not react with freshly precipitated copper dihydroxide?
propanone
Which chain of chemical reactions is not possible?
C2H5OH → C2H5CHO → C2H5COOH
Optical isomerism is not characteristic of:
2-amino-2-methylpropanoic acid
The molecular formula C6H12O6 corresponds to the compounds:
glucose and fructose
Cellulose dissolves in:
Schweitzer’s reagent
From which compound is hexan-3-one obtained as the only organic product under the conditions of the Kucherov reaction?
CH3CH2C=-CCH2CH3
Reagent for qualitative identification of ethylene glycol is:
freshly precipitated Cu(OH)2
The chain-radical halogenation of alkanes occurs under the action of:
diffuse sunlight
The compounds (E)-3-methylhex-3-ene and (Z)-hept-2-ene are:
constitutional (structural) isomers
Ethanol has a lower boiling point than water because…
the attraction between the molecules is weaker
Give the IUPAC name of this compound: CH3OCH2CH3
methoxyethane
The segment -CH2CH2CH2CH2CH2CH2- represents the polymer named:
polyethylene
Which of the following reacts with [Ag(NH3)2] giving a white precipitate:
CH3CH2C=-CH
Which of the following is a correct name for (CH3)2CHCOCH3?
4-methyl-3-penten-2-one
As a result of the interaction of acetylene with water in the presence of salts of divalent mercury ions, the following is formed:
CH3CHO
Linolenic acid as opposed to stearic acid:
decolourised bromine water