Chemistry mistake questions

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75 Terms

1
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Which reagent can be used to distinguish phenol from benzyl alcohol?

FeCl3

2
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Salicylic acid is stronger than benzoic acid because:

an intramolecular hydrogen bond is formed between the two functional groups

3
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Phenols are more acidic than alcohols because:

the phenoxide ion is stabilised by resonance

4
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The strongest acid among the following aromatic compounds is:

ortho-nitrophenol

5
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What is the common name for CH2=CHCH2Cl:

allyl chloride

6
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Which reagent cannot be used for preparing alkyl chlorides from alcohols?

NaCl

7
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The reactivity of alkyl halides decreases in the following order:

RI>RBr>RCl>RF

8
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Which compound is a homologue of ethanal?

methanal

9
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Which compound contains an asymmetric (chiral) carbon atom

2-bromobutane

10
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The hydrolysis of 4-chlorobenzyl chloride with a concentrated solution of sodium hydroxide results in:

p-hydroxybenzyl alcohol

11
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The polyvalent alcohols are identified with:

freshly precipitated copper (II) hydroxide

12
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The reactions by which m-nitrophenol can be produced from benzene are:

sulfonation, nitration, reaction with sodium hydroxide, alkali melting

13
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The mild oxidation of which alcohol does not give a carbonyl compound?

2,3-dimethyl-3-pentanol

14
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Which pair are metamers?

CH3OCH2CH2CH3 and CH3CH2OCH2CH3

15
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How a solution containing benzene, naphthalene, phenol and aniline can be separated:

the phenol is extracted after treatment with sodium hydroxide, the aniline is extracted after treatment with hydrochloric acid, and benzene and naphthalene are extracted through distillation

16
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Which halogen notably does not react with methane by the chain-linking mechanism?

iodine

17
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Hexane may be obtained in highest yield by Wurtz method from:

1-chloropropane

18
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The amino acids do not interact with

salts

19
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Which of the following compounds is a product of the interaction between glucose and Fehling’s reagent:

CH2OH(CHOH)4COOH

20
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Which of the following compounds contains an aldehyde group:

all listed compounds

21
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How many carbon atoms in the molecule of acrylonitrile are in the sp-hybrid state

one

22
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The maltose is:

a dissacharide consisting of glucose residues, an intermediate in the hydrolysis of starch

23
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Which of the listed compounds interacts with bromine water?

ethyn

24
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Characteristic reactions for alkenes are:

addition

25
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As a result in the reaction of polycondensation is formed:

phenol formaldehyde resin

26
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Upon interaction of phenol with bromine is formed a mixture of:

2- and 4- bromophenols

27
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By the help of which reagent may 1-propanol and 1,2,3-propantriol be distinguished?

copper (II) hydroxide

28
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Which of the following amino acids is achiral?

glycine

29
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By which of the presented processes and interactions can formic acid be distinguished from ethanoic acid?

cuprum dihydroxide

30
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With which of the compounds: ethanol, sodium hydroxide and acetic anhydride, interacts with salicylic acid?

sodium hydroxide, ethanol and acetic anhydride

31
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Which of the folllowing will give 1-butene as the only alkene by heating with concentrated sulfuric acid?

1-butanol

32
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Glucose and fructose may be distinguished by interaction with:

bromine water

33
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Which is not a physical property of alcohols or phenols?

the hydroxyl group of an alcohol is nonpolar

34
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The benzene ring of benzaldehyde substitutes at m-position to the aldehyde group, because it has:

-M and -I effect

35
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Carbonyl derivatives do not add one of the following substances:

bromine

36
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The molecular formula of glycerol is:

C3H5(OH)3

37
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The interaction between which substances is an addition reaction?

ethanal and hydrogen

38
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The colourless crystalline substance A is slightly soluble in water, it sublimes when heated, and 2 mol of NaOH are needed for the neutralisation of 1 mol of A

Substance A is:

salicylic acid

39
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Which of the reagents can be used to identify glycerol

with an aqueous solution of FeCl3 - violet colouring

40
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Sucrose is a carbohydrate. The molecular formula of the compound is:

C12H22O11

41
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The use of fats with alkaline base in an aqueous medium during heating is used in the production of:

soaps

42
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Oxidation of butanone produces:

acetic and propionic acids, CO2 and H2O

43
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In which order are carboxylic acids arranged by increasing their acidic properties?

propionic, acetic, benzoic, formic

44
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The vigorous oxidation of which isomer of hexene does not result in a mixture of acids?

3-hexene

45
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In which order are the compounds arranged in order of increasing reactivity?

CH3COC2H5, CH3COCH3, CH3CHO, HCHO

46
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Under what conditions can hydrogen atoms in the side chain of toluene be replaced by atoms of halogen elements?

under illumination at high temperature

47
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A natural polymer is:

the rubber

48
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Hydrogen bonds can not form between molecules of:

CH3CHO and CH3COCH3

49
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Oxidation of ethylene (CH2=CH2) produces:

1,2-ethanediol

50
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A phenolic hydroxyl group can be identified with a dilute aqueous solution of:

FeCl3

51
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The equation: C2H5OH + HCOOH →←HCOOC2H5 + H2O expresses the process:

esterification

52
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In the molecules of alpha-amino acids the groups -NH2 and -COOH are connected to:

the first carbon atom

53
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Which of the following compounds does not react with an ammonia solution of Ag2O?

3-hexanone

54
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The two functional groups in alpha-amino acids interact with each other and form intramolecular salts. It is due to…

the high solubility in water, the high melting point and the low solubility in organic solvents

55
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In which hydrocarbon conversion process do the final products contain a greater number of carbon atoms than the starting substances?

Wurtz synthesis

56
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Polymethyl methacrylate is obtained by polymerisation of:

CH2=C(CH3)COOCH3

57
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Benzaldehyde is involved in substitution reactions affecting the aromatic nucleus. In which place are the substitutes oriented:

m-position

58
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Which of the following acids has optical isomers?

lactic acid

59
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Positional isomerism is possible with:

amino acids, ketones, alkynes

60
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Which of the following substances does not react with freshly precipitated copper dihydroxide?

propanone

61
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Which chain of chemical reactions is not possible?

C2H5OH → C2H5CHO → C2H5COOH

62
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Optical isomerism is not characteristic of:

2-amino-2-methylpropanoic acid

63
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The molecular formula C6H12O6 corresponds to the compounds:

glucose and fructose

64
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Cellulose dissolves in:

Schweitzer’s reagent

65
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From which compound is hexan-3-one obtained as the only organic product under the conditions of the Kucherov reaction?

CH3CH2C=-CCH2CH3

66
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Reagent for qualitative identification of ethylene glycol is:

freshly precipitated Cu(OH)2

67
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The chain-radical halogenation of alkanes occurs under the action of:

diffuse sunlight

68
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The compounds (E)-3-methylhex-3-ene and (Z)-hept-2-ene are:

constitutional (structural) isomers

69
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Ethanol has a lower boiling point than water because…

the attraction between the molecules is weaker

70
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Give the IUPAC name of this compound: CH3OCH2CH3

methoxyethane

71
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The segment -CH2CH2CH2CH2CH2CH2- represents the polymer named:

polyethylene

72
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Which of the following reacts with [Ag(NH3)2] giving a white precipitate:

CH3CH2C=-CH

73
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Which of the following is a correct name for (CH3)2CHCOCH3?

4-methyl-3-penten-2-one

74
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As a result of the interaction of acetylene with water in the presence of salts of divalent mercury ions, the following is formed:

CH3CHO

75
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Linolenic acid as opposed to stearic acid:

decolourised bromine water