Alcohols, Carboxylic Acids, Esters, Polymers

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33 Terms

1
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What are alcohols?

Compounds with the hydroxyl (-OH) functional group, which is covalently bonded to the carbon atom and does not dissociate in water

2
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What is the general formula for alcohols

Cn H2n+1 OH

3
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Describe the melting and boiling points of alcohols

  • Increases down the homologous series

  • Molecular size increases → strength of IMF increases

  • More energy is needed to overcome stronger IMF between molecules

4
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Describe the solubility of alcohols in water

  • Decreases down the homologous series

    • First few are soluble

  • Carbon chain length increases → hydrophobic character increases

    • Shorter-chain alcohols are volatile liquids at r.t.p. and pressure

5
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What are the conditions for combustion with alcohols?

  • Limited oxygen (incomplete combustion)

  • Excess oxygen (complete combustion)

6
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Describe the flammability of alcohols

More flammable than alkanes due to O in OH functional group

7
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What are the conditions for oxidation of alcohols?

Heat under reflux with an oxidizing agent e.g. acidified KMnO4 that supplies oxygen atoms

C2H5OH + 2O2 → CH3COOH + H2O

8
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What are the conditions of hydration to form alcohols?

  • 300ºc

  • 60atm

  • H3PO4 [phosphoric (V) acid] as a catalyst

9
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What are the conditions for the fermentation of alcohols?

  • 37ºc

  • Yeast catalyst

  • Absence of oxygen

10
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What is the products of the fermentation of alcohol?

Ethanol + CO2

11
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What is the fermentation of alcohol for?

  • Making ethanol only

  • Distillation can give pure and concentrated ethanol despite it being diluted

12
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What is the general formula for carboxylic acids

Cn H2n+1 COOH

13
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What are carboxylic acids?

Organic compounds with the carboxyl (-COOH) functional group

*Weak acids

14
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What are the physical properties of carboxylic acids?

  • All soluble in water

  • High boiling and melting points as compared to alcohols and hydrocarbons

15
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What are the conditions and products for the carboxylic acid + reactive metal reaction

  • Metals have to be above hydrogen in the reactivity series

  • Carboxylate salt + H2

  • 2CH3COOH + Ca -> (CH3COO)2 Ca [calcium ethanoate] + H2

16
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What are the conditions and products for the carboxylic acid + carbonate reaction

  • No conditions

  • Carboxylate salt + CO2 + H2O

  • 2CH3COOH + Na2CO3 → 2CH3COONa [sodium ethanoate] + CO2 + H2O

17
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What is CaCO3 also known as?

Marble chips

18
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What can carboxylic acids react with?

  • Acid / base

  • Carbonate

  • Reactive metal

19
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What are the conditions and products for the carboxylic acid + acid / base reaction

  • No conditions

  • Carboxylate salt + H2O

20
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What are esters?

Generally sweet-smelling compounds with small molecular sizes formed from the reaction of alcohols and carboxylic acids

21
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What is the functional group for esters?

-COO

22
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What is the general formula for esters?

Cn H2n+1 CO OCm H2m+1

  • Derived from carboxylic acid

  • Derived from alcohol

23
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C2H5OH (ethanol) + HCOOH (methanol acid) →

[HCOOC2H5] Ethyl methanoate

*refer to notes for more

24
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What are the conditions for esterification?

Concentrated sulfuric acid catalyst

25
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What are polymers?

Large organic molecules containing thousands or millions of atoms formed when many small molecules, monomers, join through polymerization

26
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What is addition polymerization?

Unsaturated monomers join without losing any molecules to form addition polymers

27
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What are the conditions for addition polymerization?

  • High temperature and pressure

  • Catalyst

28
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How does addition polymerization occur?

knowt flashcard image
29
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What is condensation polymerization?

Monomers combine to form condensation polymers with the removal of small molecules like water

30
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What are the monomers of polyamides like nylon?

Dicarboxylic acid and diamine

31
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What are the monomers of polyesters like terylene

Dicarboxylic acid and diol

32
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What is the linkage in polyamides and polyesters respectively?

Polyamides → Amide linkage

Polyesters → Ester linkage

33
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What are examples of addition polymers?

  • Polyethene

  • Polystyrene

  • Polyvinyl chloride