Classification of Elements and Periodicity in Properties

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48 Terms

1
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Dobereiner's Law of Triads

the atomic mass of the central atom is the arithmetic mean of the atomic masses of the other two elements

2
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AEB de Chancourtois

Telluric Helix

3
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Newland's Law of Octaves

In a set of eight elements, the 1st and 8th element have similar characteristics.

worked for lighter elements only, up until Ca

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Lothar Meyer

1. plotted graph between atomic volume and atomic weight

2. most electropositive elements at peaks of curves

3. less strongly electropositive elements occupy the DESCENDING portion of the curves

4. most electronegative elements occupy the ASCENDING position of the curves

5. transition metals occupy the TROUGHS of the curves

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"the properties of elements are a periodic function of their atomic weights."

mendeleev

6
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eka-aluminum

Gallium

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eka-silicon

germanium

8
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"the physical and chemical properties of elements are periodic functions of their atomic numbers."

Henry Moseley

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What concept is the modern Periodic table based on

Bohr-Bury concept

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How many periods are on the periodic table?

7

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How many groups are on the periodic table?

18

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Number of elements in each period

1st period: 2
2nd period: 8
3rd period: 8
4th period: 18
5th period: 18
6th period: 32
7th period: not complete, can fit 32

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pseudo transition elements

Zn, Cd, Hg

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Lanthanides

Ce(58) - Lu (71)

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Actinoids

Tho(90) - Lr (103)

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metalloids (semimetals)

silicon, arsenic, germanium, tellurium, antimony

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Are covalent radii are van der Waals radii larger

van der Waals radii

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van der waals, covalent and metallic radii size

van der Waals > metallic > covalent

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which elements have the largest radii in their respective periods

nobel gases

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Is ionization energy endothermic or exothermic?

endothermic

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Does B have a higher ionisation enthalpy or does Be have a higher ionisation enthalpy

Be

(exception)

removing electron from 2s is harder than removing from 2p

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Does beryllium show positive electron gain enthalpy

yes

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Does neon show negative electron gain enthalpy

no

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does nitrogen show positive electron gain enthalpy

yes

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does fluorine or chlorine have a higher electron gain enthalpy

florine

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which has a higher negative electron gain enthalpy, sulphur or oxygen

sulphur

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Electronegativity (Mulliken scale)

(IE1 + IE2)/ 2

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Pauling Scale of Electronegativity

Mulliken scale/ 2.89j

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Lithium has a diagonal relationship with

Mg

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Beryllium has a diagonal relationship with

Al

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Boron has a diagonal relationship with

Si

32
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Covalency of first members of each group

4

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Which elements form pπ-pπ bonds

all of the first members of the p-block elements form these bonds with themselves, or with other first members of other groups of p-block

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Cl₂O₇ + H₂O

2HClO₄
(perchloric acid)

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Na₂O + H₂O

2NaOH

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Most electropositive element

Caesium

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most dense element

iridium

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best electrical conductor

silver

39
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which element shows the maximum number of isotopes

tin

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in each period, second IE is greatest in which group

1st

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in each period, third IE is greatest in which group

2nd

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which element has the highest IE

He

43
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Which element has the highest MP among metals

W

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among all the elements, which has the highest MP

diamond (C)

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elements of F block belong to which group

3

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radioactive lanthanide

promethium (61)

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element 118

last element in group 18
(period 7)

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how many elements are in 4f and 5f each

14