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Quaternary Structure
Protein–Protein Interactions; same interactions that stabilize tertiary structure, but between multiple protein subunits
Why Quaternary Structures?
New structural properties (especially fibrous proteins)
Improved regulation (allostery)
Link functions in close proximity (multi-enzyme complex)
Symmetries of quaternary structures
Although composed of asymmetric polypeptides, proteins adopt many symmetrical patterns
ex. Helical Symmetry (Tobacco mosaic virus: protein subunits form a helical array about a helically coiled RNA)
Protein protein interactions
Bovine Pancreatic Trypsin Inhibitor with trypsin
Hetero-oligomers
different proteins come together
G-protein complex: Heterotrimeric
haemoglobin: heterotetrameric note symmetry
Homo-oligomers
same proteins come together
DNA packaging motor - homodecamer
Virus Capsids
very intricate quaternary structures