L10-stereochemistry 3

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4 Terms

1
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What do you call/ how do you describe a chiral centre

Specific atoms are sterogenic and molecules are chiral

2
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What are the CIP rules for determining how an enantiomer rotates

  1. assign priority according to atomic number 

  2. if a decision cant be made with the first atom look at second then third ect 

  3. double bonds count as two atoms/sigma bonds same for triple but lone paris coumt as zero 

  4. orientate the 4th atom at the back and then follow the sequence 

anticlockwise=S

clockwise=R

3
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explain how re and si faces work and the difference between using R and S to describe

re and si describes the faces of the molecule

re describes the back face

si describes the front face 

4
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explain what the use of the CIP rules are 

They are used to determine the configuration of an enantiomer and distinguish between mirror images