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Boyle’s Law
P1V1 = P2V2
Charles’s Law
V1/T1 = V2/T2
Gay-Lussac’s Law
P1/T1 = P2/T2
The Combined Gas Law
P1V1/T1 = P2V2/T2
Daltons Law
Ptotal = P1 + P2 + P3 + …
Mole fraction
PA = XA*Ptotal where XA= molA/moltotal
Ideal Gas Law
PV = nRT
Ideal Gas Law: when P is atm, R is
0.08206
Ideal Gas Law: when P is kPa, R is
8.314
Ideal Gas Law: when P is mmHg, R is
62.4
(Use when asked to solve problems involving density of a gas or to identify it based on calculation of its molar mass)
PV = nRT where n = mass/MM
PV = (mass/MM) RT
(Use when asked to solve problems involving density of a gas or to identify it based on calculation of its molar mass)
MM = (mass*RT)/PV where D = mass / V
MM = (DRT) / P
STP
Standard Temperature and Pressure
Standard Pressure
1 atm = 760 torr = 760 mmHg = 101.3 kPa
Standard Temperature
0oC = 273 K
Boyle’s Law : Inverse or Direct
Inverse
Charles’s Law: Inverse or Direct
Direct
When to use Boyle’s Law?
For a given mass at constant temperature
When to use Charles’s Law
Pressure is constant
When to use Gay-Lussac’s Law
When volume is constant
Gay-Lussac’s Law: Inverse or Direct
Direct
When to use the Combined Gas Law?
Amount of gas is constant