Solute
The substance (solid) that is dissolved in the solvent.
Solvent
The liquid that dissolves the solute, present in greatest abundance.
Solution
A homogeneous mixture of two or more pure substances.
Aqueous Solution
A solution where water is the solvent.
Molarity (M) Defined
The concentration of a solution expressed as moles of solute per liter of solution.
Molarity Formula
M=\dfrac{n}{V} where volume in in liters
Dilution Formula
McVc = MdVd, where Mc and Md are molarities and Vc and Vd are volumes of concentrated ( c ) and dilute ( d ) solutions.
Strong Acids
Acids that completely dissociate in solution, e.g., HCl, HBr, HI, HClO3, HClO4, HNO3, H2SO4.
Weak Acids
Acids that partially dissociate in solution, e.g., HF, CH₃COOH.
Strong Bases
Bases that completely dissociate in solution, including Group 1A metal hydroxides and heavy Group 2A metal hydroxides.
Oxidation State
The charge of an atom in a compound, with specific rules for different groups.
Balancing Redox Reactions
The process of dividing reactions into half reactions and balancing them for atoms and charge.
Acidic Solutions
Combine half reactions and cancel common terms.
Basic Solutions
Add OH- to balance H+, forming H2O, then combine half reactions.
Change in Internal Enthalpy (ΔE)
The difference in energy between products and reactants, E_{products}-E_{reactants}
Exchange of Energy
ΔE = q + w, where q is heat and w is work.
Endothermic Reaction
A reaction where ΔE > 0, indicating energy absorption.
Exothermic Reaction
A reaction where ΔE < 0, indicating energy release.
Enthalpy (H)
The total energy of a system, including internal energy and pressure-volume work.
Change in Enthalpy (ΔH)
ΔH = ΔE + PΔV, representing the change in enthalpy during a reaction.
Work (w)
PV or -PV, where P is pressure and V is volume.
Specific of Light
c = λv, where c is the speed of light, λ is wavelength, and v is frequency.
Speed of Light (c) constant
A constant value of 3.00 × 108 m/s.
Energy in proportional to frequency
E = hv, where E is energy, h is Planck’s constant, and v is frequency.
Enthalpy of Reaction
\Delta H_{rxn}=H_{products}+H_{reactants}
Planck’s Constant (h)
A constant value of 6.626 × 10-34 J·s.
Fahrenheit Conversion
F = (9/5)(°C + 32).
Celsius Conversion
C = (5/9)(°F - 32).
Kelvin Conversion
K = °C + 273.