Chemistry - Chapter 4 Section Test

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The test is Multiple Choice

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53 Terms

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How many orbitals fill electrons?

Depends on sublevel — s: 1, p: 3, d: 5, f: 7.

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What shapes do you need to know for orbitals?

s = sphere, p = dumbbell, d = clover, f = complex.

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Bohr model

how electrons behave in atoms.

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electromagnetic radiation

a form of energy that exhibits wavelike behavior as it travels through space

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electromagnetic spectrum

all forms of electromagnetic radiation

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wavelength

the distance between corresponding points on the adjacent waves

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frequency

the number of waves that pass a given point in a specific time

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photoelectric effect

the emission of electrons from a metal when light shines on meta

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quantum

the minimum quantity of energy that can be lost or gained by an atom

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photon

a particle of electromagnetic radiation having zero mass and carrying a quantum energy

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ground state

lowest energy state of an atom

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excited state

a state in which an atom has a higher potential energy than it has in its ground state

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line-emission spectrum

a diagram/graph that indicates the degree to which a substance emits radiant energy with respect to wavelength

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continuous spectrum

the emission of a continuous range of frequencies of electromagnetic radiation

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heisenberg uncertainty principle

states that it is impossible to determine simultaneously both the position and velocity of an electron or any other small particle

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quantum theory

describes mathematically the wave properties of electrons and other very small particles

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orbital

indicates the probable location of an electron

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quantum number

specify the properties of atomic orbitals and the properties of electrons in orbitals

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principle quantum number

symbolized by n, indicates that main energy level occupied by an electron

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angular momentum (orbital) quantum number

symbolized by L, indicates the shape of the orbital

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magnetic quantum number

symbolized by m, indicated the orientation (location) of an orbital around the nucleus

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spin quantum number

has only 2 possible values (+1/2, -1/2) which indicate the 2 fundamental spin states of an electron in an orbital

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electron configuration

the arrangements of an electron in an atom

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aufbau principle

an electron occupies the lowest energy orbital that can receive it

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pauli exclusion principle

no 2 electrons in the same atom can have the same set of 4 quantum numbers

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hund's rule

Electrons fill orbitals one at a time before pairing up, and single electrons in the same type of orbital spin in the same direction.

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noble gas

group of 18 elements

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noble-gas configuration

refers to an outer main energy level occupied, in most cases by 8 electrons

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When going from excited to ground state, energy…?

Decreases

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When going from ground to excited state, energy…?

Increases

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When going from excited to ground state, energy…?

Speed of light.

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Even numbers represent what?

Electrons

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Odd numbers represent what?

Orbitals.

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What do S, P, D represent?

Sublevels or shapes of orbitals.

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How many electrons can each shape hold?

s = 2, p = 6, d = 10, f = 14.

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What is the unit for frequency?

Hertz (Hz).

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Quantum numbers tell you what?

Location and properties of electrons

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Can there be an 8s orbital?

Yes.

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Number of sublevels = ?

Energy level number (n)

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What are “The Rules”?

  • Aufbau: lowest energy first.

  • Pauli: 2 electrons per orbital (opposite spins).

  • Hund’s: fill orbitals singly first (same spin).

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How many orientations can an orbital have?

s = 1, p = 3, d = 5, f = 7.

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Radiation types (X-ray, gamma, UV, etc.) all travel at what speed?

The speed of light.

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Who is “Louie” (de Broglie)?

He said electrons act like waves.

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Where are electrons most likely found?

Electron cloud.

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What are photons and quanta?

Tiny packets of light energy.

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Formula: wavelength × frequency = ?

Speed of light (c).

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How many possible spin states?

2 (↑ or ↓). (positive or negative)

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Formula n² = ?

Number of orbitals per energy level.

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Formula 2n² = ?

Maximum number of electrons per energy level.

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What is the orbital angular momentum number

It tells the shape of the orbital

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What is the magnetic quantum number

It tells the orientation of the orbital in space.

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What is the spin quantum number

It tells the direction of the electron’s spin.

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Compared with an electron for which n = 2, an electron for which n = 4 has more